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Scientists have found further evidence for the existence of an elusive intermediate implicated in chemical reactions that degrade atmospheric pollutants. A new method of directly detecting the simplest form of this intermediate, as well as more measurements of the intermediate’s reactivity, provide indications that atmospheric models need to improve how they account for them.More than 50 years ago, German chemist Rudolf Criegee proposed that alkenes in the atmosphere, released either by plants or human activities, degrade by reacting with ozone to form a cyclic ozonide. One of the products formed when this ozonide falls apart is a carbonyl oxide called...

Scientists have shown that a newly discovered molecule in Earth's atmosphere has the potential to play a significant role in off-setting global warming by cooling the planet. In a breakthrough paper published in Science, researchers from The University of Manchester, The University of Bristol and Sandia National Laboratories report the potentially revolutionary effects of Criegee biradicals. These invisible chemical intermediates are powerful oxidisers of pollutants such as nitrogen dioxide and sulfur dioxide, produced by combustion, and can naturally clean up the atmosphere. Although these chemical intermediates were hypothesised in the 1950s, it is only now that they have been detected....