A chilling look inside the minds of female prisoners unfolds on Thursday with the première of the new TLC show, Prison Diaries. The first episode of the series focuses on Emilia Carr, one of just 63 women on death row in the U.S. Carr is seen in ankle chains and handcuffs, led by a burly, fully-armed female guard as she leaves her cell. She wears bright orange overalls and trainers, her long, dark hair allowed to fall around her hunched shoulders.