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The Science Behind Why Dark Chocolate Is So Bitter
Sciencing ^ | March 31, 2025 | Joe Roberts

Posted on 04/03/2025 8:05:27 PM PDT by Red Badger

Once used as offerings to the gods and as a form of currency by the Olmecs, Mayans, and Aztecs, cacao beans have taken on a different value in modern society. Today, these beans are the basis of all the chocolate we love so much, but it has taken centuries for chocolate to become the ubiquitous treat we know it as.

In the time when the Mayans drank cacao beans in liquid form, they were considered savory, with the beans being ground with maize and mixed with water. Considering chocolate contains many chemical compounds with a distinctly bitter taste, it's not all that surprising that the Mayans didn't initially think to use cacao as the basis of what we now think of as a go-to dessert ingredient. This changed fairly quickly however, with sugar and spices ultimately being added to the mixture to make it more pleasing.

Since then, the way chocolate is prepared has changed significantly, but the practice of adding sugar to balance out the inherent bitterness has remained the same. Even the dark chocolate, while much more bitter than milk chocolate, is still typically balanced with some sort of sweetener. But what exactly makes the cacao beans so bitter in the first place? Here's everything you need to know about the bitterness of dark chocolate.

Chocolate is made using processed cacao beans

To understand what gives chocolate its inherent bitterness, it's helpful to understand just how it's made. Cacao beans come from the Theobroma cacao tree, on which large fruits grow. These pod-like fruits contain between 20 and 60 beans each and it's these beans — which are fermented, dried, roasted, and ground — that are used to make chocolate. Processed cacao beans are used to produce two main components: cocoa solids and cocoa butter. Cocoa butter is the fat and is used by itself to make white chocolate. The butter doesn't affect overall flavor, but cocoa solids are what gives the chocolate its color and flavor.

After the cacao beans have been processed, other ingredients are mixed with the cocoa solids and butter, and this is where the main difference between milk chocolate and dark chocolate emerges. Typically, the processed cacao beans are mixed with some combination of sugar, emulsifiers, aroma, and milk before the mixture goes through conching and tempering. But the amount of extra ingredients used is what separates dark chocolate from other types.

More cocoa in dark chocolate means more bitterness

We all have our own preferences when it comes to chocolate, with milk chocolate being by far the most popular. But many prefer a more robust and slightly more bitter form of this beloved treat, and that's where dark chocolate comes in. This form of chocolate is designed to highlight the natural bitterness of cocoa, which is achieved in part by using more cocoa solids in the mixture. These solids contain the essence of the cacao bean and are packed with flavonols, a type of antioxidant plant compound. The flavanols contain much of chocolate's innate bitterness, and since dark chocolate uses more cocoa solids, and therefore more flavanols, it has less room for sugar, making for a distinctly bitter taste.

Typically, dark chocolate is made of just cocoa mass and cocoa butter which is balanced by sugar. No milk is used in the production of dark chocolate, which will usually have a cocoa level of 70%, which means that 70% of the chocolate is made using ingredients solely from the original cacao bean, while 30% is added ingredients (usually just sugar), but some dark chocolate can go all the way to 99%, making for an even more intense bitterness.

Chocolate has plenty of bitter chemical compounds

Chocolate actually contains hundreds of chemical compounds, many of which give off a bitter taste — an adaptation that deters herbivores and frugivores from eating the seeds in the wild. Theobromine, for example, is a bitter chemical, small amounts of which are found in cacao. Theobromine has a very similar molecular structure to caffeine and affects the human body in similar ways such as widening blood vessels and acting as a stimulant. Caffeine can also be found in chocolate, which as any coffee drinker will know, has a very bitter taste.

Another compound with an inherently bitter taste found in chocolate is phenylethylamine, which also has stimulating effects. Alkaloids and polyphenols in cacao beans are also generally quite bitter and alongside the bitter salts inherent in chocolate, such as magnesium, potassium, calcium, and iron, all add up to a very sharp and striking bitter flavor that is naturally present in the cacao plant, and therefore finds its way into the final chocolate product — especially dark chocolate.

The fundamental bitterness of chocolate comes from the cacao plant itself and the various chemical compounds contained in the fruit. But, there are other factors that play into the bitterness of dark chocolate.

For one thing, certain cultivars of cacao beans are naturally more bitter than others. Cacao beans vary in many ways, from aroma and color to size and flavor. The Forastero beans grown in equatorial Africa have a generally stronger flavor, a more bitter taste, and are the most widespread form of cacao beans. Criollo beans, however, are more aromatic and sweeter. Grown in South American countries such as Colombia, Peru, and Venezuela, these beans have notes of honey and red berries. There are even hybrid beans, which combine elements of both. As such, the type of bean used in chocolate production can have a significant impact on the overall bitterness of the final product.

Another factor that plays a big role in dark chocolate bitterness is preparation. There are steps chocolatiers take during the preparation process, such as roasting the cacao beans for longer and at higher temperatures, that further enhance the bitter flavors found in dark chocolate.

While the fermentation process is typically the same for milk and dark chocolate, it is worth noting that this process can also contribute to bitterness. Fermentation is an important stage that brings out more complex flavors in the cacao beans, taking them from raw and bitter to flavorful and rich. Shorter fermentation times lead to a more bitter taste but this isn't typically a method of making dark chocolate more bitter in the way that roasting and using cocoa solids are.

Read More: https://www.sciencing.com/1818533/science-why-dark-chocolate-bitter/


TOPICS: Business/Economy; Food; Health/Medicine; History
KEYWORDS: cacao; cacaobeans; chocolate; food; rawcacaonibs
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1 posted on 04/03/2025 8:05:27 PM PDT by Red Badger
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To: Diana in Wisconsin; SunkenCiv

RAW Chocolate Ping!..........................


2 posted on 04/03/2025 8:06:03 PM PDT by Red Badger (Homeless veterans camp in the streets while illegals are put up in 5 Star hotels....................)
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To: Red Badger
The Science Behind Why Dark Chocolate Is So Bitter

That's what sugar is for.

3 posted on 04/03/2025 8:07:33 PM PDT by E. Pluribus Unum (Democrats are the Party of anger, hate and violence.)
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To: E. Pluribus Unum

You will just wind up with Bitter-Sweet chocolate............


4 posted on 04/03/2025 8:10:08 PM PDT by Red Badger (Homeless veterans camp in the streets while illegals are put up in 5 Star hotels....................)
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To: Red Badger

Not from my experience. :)


5 posted on 04/03/2025 8:11:31 PM PDT by E. Pluribus Unum (Democrats are the Party of anger, hate and violence.)
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To: Red Badger

For that reason (bitter taste), I usually prefer milk chocolate. I know we’re told dark chocolate is ‘better’, but everyone has their own reactions and preferences to flavors.
Sees Candy has some good selections. Price has gone up in last 2 years. Big Sugar (brown, tan and white) strikes again!

**Not About Chocolate. However...
Same thing again, with certain commonplace fish products.
We are told that albacore is ‘better’ than plain old canned, processed tuna, but I don’t think so.

The albacore I’ve had is sort of flat in flavor - if one is making a tuna sandwich or salad. If you are cooking with it, say, adding tuna to a pot of wild rice with green onions and curry powder, the milder flavors of the albacore are probably the best choice to embrace all the neighboring flavors and spices without becoming too salty.


6 posted on 04/03/2025 8:32:15 PM PDT by lee martell
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To: E. Pluribus Unum

20+ years ago, I had a raw foodie friend who introduced me to raw cacao nibs. She put a spoonful in my hand and said try these… I spit them out. Yuck. A few years later, when chronic ill health caused me to rethink everything food, I tried them again, this time adding a tablespoon of raw nibs to fresh blueberries and a 1/4 cup of ricotta cheese. Oh wow. As good as ice cream! I now add them to cottage cheese, Icelandic yogurt with strawberries or blueberries, green avocado smoothies (add a little liquid Stevia and it tastes like chocolate milkshake), and of course, vanilla or coffee ice cream.


7 posted on 04/03/2025 8:36:25 PM PDT by ponygirl (Stay gold.)
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To: lee martell

True. Personal tastes vary significantly.
I preferred dark chocolate and black licorice even as a child.
I also drank coffee and preferred spicy foods at a very young age.
Still do.


8 posted on 04/03/2025 8:45:42 PM PDT by sjmjax
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To: sjmjax

You were ‘allowed’ to drink coffee at a young age?
Lucky you. Me and my sisters were taught how to make coffee for parents and grandparents, but not permitted to drink any until around 10 years of age. Me, being the Boy, I also had to empty my Grandad’s ashtrays and clean his smoking pipes when he would visit.


9 posted on 04/03/2025 8:52:57 PM PDT by lee martell
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To: Red Badger
Cocoa butter is the fat and is used by itself to make white chocolate.

Try and find white chocolate made with cocoa butter. In my area, I certainly can't without going to a specialty confectioner's shop.

It's all crap fats now. e.g., palm oil.

Interesting piece.

10 posted on 04/03/2025 9:26:05 PM PDT by logi_cal869 (-cynicus the "concern troll" a/o 10/03/2018 /!i!! &@$%&*(@ -)
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To: ponygirl


"raw cacao nibs"


Never heard of those.. looked them up and ordered some to try out, but a few reviews said that there were some rock hard stems and shells mixed in (not filtered).
Hopefully I won't break any teeth 😁. (BTW, 0 calories)
11 posted on 04/03/2025 9:32:14 PM PDT by Bikkuri (I am proud to be a PureBlood.)
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To: Red Badger

I have never much cared for chocolate, but I really dislike dark chocolate.


12 posted on 04/03/2025 9:37:44 PM PDT by AlaskaErik (There are three kinds of rats: Rats, Damned Rats, and DemocRats.)
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To: Red Badger

“Even the dark chocolate, while much more bitter than milk chocolate”. The Mrs. likes dark chocolate, me, gotta be milk chocolate.


13 posted on 04/03/2025 9:47:53 PM PDT by kawhill (I'm driving out of myself Tom. You know these brakes are shot Frank. I've considered that.)
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To: Red Badger
Why Dark Chocolate Is So Bitter

White Chocolate privilege?

-PJ

14 posted on 04/03/2025 9:51:35 PM PDT by Political Junkie Too ( * LAAP = Left-wing Activist Agitprop Press (formerly known as the MSM))
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To: lee martell

albacore is the chicken breast of fish..........


15 posted on 04/03/2025 9:57:15 PM PDT by Red Badger (Homeless veterans camp in the streets while illegals are put up in 5 Star hotels....................)
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To: Political Junkie Too

16 posted on 04/03/2025 10:01:31 PM PDT by Red Badger (Homeless veterans camp in the streets while illegals are put up in 5 Star hotels....................)
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To: Political Junkie Too

Lol!


17 posted on 04/03/2025 10:06:54 PM PDT by lee martell
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To: Red Badger

More cocoa, hardly any refined sugar added, if any


18 posted on 04/03/2025 10:17:22 PM PDT by Secret Agent Man (Gone Galt; not averse to Going Bronson.)
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To: E. Pluribus Unum

True.


19 posted on 04/03/2025 10:20:37 PM PDT by No name given ( Anonymous is who you’ll know me as)
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To: Bikkuri
reviews said that there were some rock hard stems and shells mixed in (not filtered). Hopefully I won't break any teeth

Yes, that can be a problem with certain brands. I have never had that problem with Navitas brand that I find at my Sprouts Market. I think they have that brand at Whole Foods also, but I don't usually shop there. Sprouts used to carry a brand (name I can't recall) in a large glass jar that was really good and no hulls, but lately I haven't been able to find it. I just ordered a two pound package from Amazon called Terra Foods. I opened the first package and there was a large hull sitting right on top, so I will have to be really careful with these... I usually only use a tablespoon or two at a time, so I spread them out in my hand to make sure there are no tooth-breaking bits.

Now if you really want something tasty, get the cacao nibs that have been toasted/roasted. OMG, they are so good on anything, but they are not "raw food," so like dry roasted nuts, they snap and crumble easier than the raw ones and have a fuller chocolate taste, more like bittersweet chocolate chips. The nibs are also a source of "good" fat.

20 posted on 04/04/2025 12:15:39 AM PDT by ponygirl (Stay gold.)
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