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What causes lithium-ion battery fires? Why are they so intense? And how should they be fought? An expert explains [Australia]
The Conversation ^ | October 4, 2023 7:49pm EDT | Staff

Posted on 12/27/2023 7:51:54 AM PST by Red Badger

Picture this: you’re cruising down the Great Ocean Road in your brand new electric vehicle (EV), the ocean to your left and the wind in your hair. But what if I told you this idyllic drive could turn into a nightmare, with the faint smell of something burning?

This month we have had at least two large lithium-ion battery fires in Australia – one in the Sydney airport car park and another one more recently at the Bouldercombe battery storage site in Queensland.

When a lithium-ion battery fire breaks out, the damage can be extensive. These fires are not only intense, they are also long-lasting and potentially toxic.

What causes these fires? Most electric vehicles humming along Australian roads are packed with lithium-ion batteries. They’re the same powerhouses that fuel our smartphones and laptops – celebrated for their ability to store heaps of energy in a small space.

The reality is lithium-ion batteries in electric vehicles are very safe. In fact, from 2010 to June 2023, only four electric vehicle battery fires had been recorded in Australia. A recent paper forecasts a possible total of around 900 EV fires between 2023 and 2050. This is, for all intents and purposes, a small amount.

Nonetheless, when EV batteries do overheat, they’re susceptible to something called “thermal runaway”. This chemical reaction can be triggered from faults in the battery – whether that’s an internal failure (such as an internal short circuit) or some kind of external damage. In extreme cases, it causes the battery to catch fire or explode.

The onset and intensification of lithium-ion battery fires can be traced to multiple causes, including user behaviour such as improper charging or physical damage.

Then there are even larger batteries, such as Megapacks, which are what recently caught fire at Bouldercombe. Megapacks are large lithium-based batteries, designed by Tesla. They are intended to function as energy storage and to help “stabilise the grid and prevent outages”.

The Megapack that caught fire on Tuesday is one of 40 lithium-ion Megapack 2.0 units on-site. A Megapack fire is daunting for obvious reasons. These have a capacity of 3 megawatt hours, which equals 3,000 kilowatts of electricity generated per hour.

It’s no surprise the Bouldercombe fire may be burning for several days.

What to do when a fire has started? If a fire bursts out in an EV or battery storage facility, the first instinct may be to grab the nearest hose. However, getting too close to the fire could spell disaster as you may be injured by jet-like flames or projectiles.

In the case of up-and-coming solid-state batteries with a lithium metal anode (instead of the more common graphite anode), these have a rather unwelcome talent for chemical reactions when they come into contact with water.

Instead of snuffing out the flames, water could actually fuel the fire and cause it to intensify. This is because the water’s reaction with the lithium can produce flammable hydrogen gas – adding more of a hazard to an already perilous situation.

While firefighters have used water on lithium-battery fires in the past (as it can help with cooling the battery itself), they have at times needed up to 40 times as much as a normal car fire requires.

It may often be safer to just let a lithium battery fire burn, as Tesla recommends in its Model 3 response guide:

Battery fires can take up to 24 hours to extinguish. Consider allowing the battery to burn while protecting exposures.

This could explain why Tesla advised authorities in Bouldercombe to not put out the blaze.

Water also conducts electricity, which means spraying it on a battery fire could lead to electrical shocks or short-circuits if the battery is not electrically isolated.

Globally, numerous solutions have been proposed for extinguishing lithium-ion battery fires. However, as of now, neither Australian standards, nor any other internationally-recognised guidelines adequately address fire extinguishing requirements for this purpose.

Importantly, the appropriate fire extinguishing method will vary depending on the type of lithium battery in question (such as lithium-ion, all-solid-state lithium-ion or lithium polymer).

For standard lithium-ion battery fires, the sprinkling of fine water mist may be used to suppress the fire. On the other hand, experts recommend using specially-designed Class D fire extinguishers for solid-state lithium-metal battery fires – or dry chemical fire extinguishers that are appropriate for electrical fires.

These contain substances, such as sodium chloride powder or pressurised argon, that can combat the challenges posed by solid-state batteries. Sodium chloride, commonly known as table salt, melts to form an oxygen-excluding crust over the fire. Similarly, argon is an inert and non-flammable gas which can help put out fires by suffocating oxygen.

That brings us to the aftermath of the fire – and another often-overlooked hazard: toxic fumes. When lithium-ion batteries catch fire in a car or at a storage site, they don’t just release smoke; they emit a cocktail of dangerous gases such as carbon monoxide, hydrogen fluoride and hydrogen chloride.

These fumes can be hazardous to your health, especially when inhaled in significant quantities. This is why these battery fires are a particular concern in confined spaces such as a garage, where noxious gases can accumulate quickly.

What to do if your car catches fire Although EV fires are very rare, if you do own an EV (or plan to in the future), there are a few steps you can take to tip the scale in your favour.

First, get to know your EV inside and out. Familiarise yourself with its safety features. Does it have a functioning thermal management system to help keep the battery cool? What about sensors that could alert you to a problem before it turns into a crisis?

Secondly, be smart about how you charge your EV. Avoid overcharging your battery as this can increase the risk of it lighting up.

If, despite your best efforts, you find yourself head-to-head with a blaze, your first course of action should be to call emergency services for professional help.

Correction: Since this article was published it has been updated in several places to better distinguish where the author is referring to solid-state (lithium anode) or lithium-ion batteries. A reference to fire risk from fast-charging batteries has also been removed.


TOPICS: Business/Economy; Health/Medicine; Military/Veterans; Travel
KEYWORDS: automotive; batteries; ev; evbattery; lithium
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1 posted on 12/27/2023 7:51:54 AM PST by Red Badger
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To: Red Badger

I think I’ll just stay away from such possibilities. This is a lottery you can’t lose if you don’t play.


2 posted on 12/27/2023 7:53:36 AM PST by SaxxonWoods (Are you ready for Black Lives MAGA? It's coming.)
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To: SaxxonWoods

Agree. No EV for me.


3 posted on 12/27/2023 7:57:23 AM PST by Signalman
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To: SaxxonWoods

> think I’ll just stay away from such possibilities. <

I agree. New technologies need a significant shakedown period. Skip that testing, and bad things can happen.

Exhibit A: The Covid vaccine rush out.
Exhibit B: The EV rush out.
Exhibit C: My first marriage.


4 posted on 12/27/2023 8:00:46 AM PST by Leaning Right (The steal is real.)
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To: Red Badger

I’m not anti EV. It’s a promising technology that even if it doesn’t progress as fast as we’d like can fill a role in the total energy consumption picture.

What I’m against is corrupt morons forcing the public into immature technology that isn’t fit for many of the roles that consumers are looking to fill.


5 posted on 12/27/2023 8:01:46 AM PST by brownsfan (It's going to take real, serious, hard times to wake the American public.)
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To: Red Badger

Any Short Circuit in the battery can start a chain reaction.

Find an charged old lithium battery and hammer a nail in it. Instant fire.


6 posted on 12/27/2023 8:06:15 AM PST by ImJustAnotherOkie
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To: brownsfan

EV’s themselves aren’t the problem. It’s the batteries that are the problem.


7 posted on 12/27/2023 8:06:59 AM PST by ImJustAnotherOkie
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To: Red Badger

What can you do to prevent your EV from burning up?
1. Get to know your EV inside and out. Familiarise yourself with its safety features.

2. Be smart about how you charge your EV. Avoid overcharging your battery.

LOL…in other words, the short answer is NOTHING. Just pray.

We’ve been warned for decades to not top off our gas tanks, but that means the last 0.1% of fuel tank volume. For EVs, it probably means the last 10% of capacity. Since charging is automated, why would the user have to worry about overcharging, anyway? My simplest rechargeable battery powered devices have smart charging and do not overcharge. I sure don’t want to wake up at 3 am to yank the charger out of my EV.


8 posted on 12/27/2023 8:11:15 AM PST by ProtectOurFreedom (“Occupy your mind with good thoughts or your enemy will fill them with bad ones.” ~ Thomas More)
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To: Red Badger

If the Left’s dream comes true and every car is an EV you will not see your hand in-front of your face because of all the toxic smoke


9 posted on 12/27/2023 8:11:54 AM PST by butlerweave
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To: Red Badger
The reality is lithium-ion batteries in electric vehicles are very safe.

In other words, "Mostly Harmless."


10 posted on 12/27/2023 8:17:35 AM PST by Bloody Sam Roberts (The Truth is like a lion. You don't need to defend it. Let it loose and it will defend itself.)
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To: Red Badger

I see sailboat owners switching to cheap, light-weight Chinese lithium batteries…

And it strikes me as a big risk off-shore.

Especially if water can’t put it out.

I did see one s/v that had the battery to hold lithium batteries below water level, where it could be flooded if necessary…

But maybe that doesn’t work?


11 posted on 12/27/2023 8:18:11 AM PST by aMorePerfectUnion (I didn't come here to guide lambs, but to awaken lions 🦅 MAGADONIAN ⚔️)
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To: All
Picture this: you’re cruising down the Great Ocean Road in your brand new electric vehicle (EV)

I can't. Even if I try, I can't.
12 posted on 12/27/2023 8:22:34 AM PST by mmichaels1970
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To: Red Badger

[[And how should they be fought?]]

Muay Thai


13 posted on 12/27/2023 8:23:19 AM PST by Bob434
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To: Leaning Right

>> Exhibit C: My first marriage.

ROFL! The “practice marriage”.


14 posted on 12/27/2023 8:25:59 AM PST by Nervous Tick ("First the Saturday people, then the Sunday people...": ISLAM is the problem!)
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To: aMorePerfectUnion

https://www.theautopian.com/watching-a-tesla-model-x-burn-underwater-is-baffling/#:~:text=On%20Sunday%20Oct%201st%2C%20a,an%20extended%20period%20of%20time.


15 posted on 12/27/2023 8:26:46 AM PST by Red Badger (Homeless veterans camp in the streets while l aliens are put up in hotels.....................)
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To: Bloody Sam Roberts

Safe and effective..................


16 posted on 12/27/2023 8:28:03 AM PST by Red Badger (Homeless veterans camp in the streets while l aliens are put up in hotels.....................)
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To: Red Badger

Thanks RB. I hadn’t seen that.

Seems the only real viable option is to jettison it overboard


17 posted on 12/27/2023 8:31:06 AM PST by aMorePerfectUnion (I didn't come here to guide lambs, but to awaken lions 🦅 MAGADONIAN ⚔️)
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To: Red Badger

When insurance companies unite to refuse to insure electric vehicles, the market will collapse. It has already begun the death spiral.


18 posted on 12/27/2023 8:33:53 AM PST by Gnome1949
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To: Red Badger

How much notice will we get if we look for temp increase?


19 posted on 12/27/2023 8:36:34 AM PST by George from New England
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To: Red Badger

How about a fire suffocation blanket over the top with a hose introducing CO2. Leave it to cool/melt down for 48 hrs.


20 posted on 12/27/2023 8:36:46 AM PST by lurk (u)
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