Posted on 02/26/2025 6:04:03 AM PST by Red Badger
Researchers discovered a tiny droplet of acid could do the job of large amounts of harmful chemicals usually used for turning aluminum transparent. (fotaro100/Shutterstock)
===================================================================
In a nutshell
* Scientists have developed a technique to transform aluminum into transparent aluminum oxide using just a droplet of acid and low voltage (2V), dramatically reducing chemical waste compared to traditional methods that require full immersion in acid baths.
* The transparent material allows more than 70% of visible light to pass through while blocking some near-infrared light, making it potentially valuable for applications in electronics, solar panels, optical sensors, and energy-efficient windows.
* This “droplet-scale anodization” technique creates highly precise transparent spots with smoother surfaces than conventional methods, and could be extended to other metals to create various transparent metal oxides with minimal environmental impact.
========================================================================
QUEZON CITY, Philippines — A single droplet of acid, a small electrical current, and ten minutes are the surprisingly modest ingredients needed to turn aluminum, one of the world’s most common metals, into a transparent material that could revolutionize electronics manufacturing. Scientists have developed this remarkably straightforward technique that drastically reduces the chemicals needed to create transparent components for everything from smartphone screens to solar panels.
The research, published in the journal Langmuir, was conducted by scientists from the Nara Institute of Science and Technology in Japan and the Ateneo de Manila University in the Philippines. Results show that it’s possible to create highly transparent aluminum oxide spots with precision and control using a fraction of the chemicals typically required in traditional manufacturing processes.
For the Sake of Transparency
Most people likely don’t think much about transparent materials when using their electronic devices. Yet the touch screen on your phone, the protective glass on your solar panels, and many optical components in cameras rely on transparent metal oxides. Creating these materials has traditionally required expensive vacuum-based techniques or large quantities of harsh chemicals, with significant environmental downsides.
This new approach boasts simplicity in addition to its environmental benefits. Rather than immersing entire aluminum sheets in vats of acid, the conventional “beaker-scale” approach, the researchers used a single microdroplet of sulfuric acid solution strategically placed on an aluminum surface. When a low voltage (just 2 volts) was applied for 10 minutes, the aluminum underneath the droplet transformed into a highly transparent circular spot.
Researchers from the Ateneo de Manila University and the Nara Institute of Science and Technology made transparent aluminum oxide (TAlOx) by applying microdroplets of acidic solution onto ordinary aluminum and applying a controlled electric current. (Credit: Budlayan et al., 2025)
==================================================================
This droplet-scale anodization technique can be extended to other transparent metal oxides, providing an environmentally friendly and cost-effective fabrication route toward sustainable electronics and other related applications.
Anodization is an electrochemical process that converts a metal surface into a durable, corrosion-resistant oxide layer. While anodization has been used for decades, this research introduces a novel approach by miniaturizing the reaction zone to just a single droplet.
Looking at the transformation under a microscope revealed something fascinating: the aluminum didn’t turn transparent all at once. Instead, it began changing at the edges of the acid droplet first, with the transparency slowly creeping inward like a clearing fog. This created a perfect circular transparent spot, and researchers found they could control both its size and quality by adjusting two simple factors: the voltage and how long they let the process run.
How Did Scientists Create the Clear Aluminum?
The team tested different electrical settings to find the perfect balance. At 3 volts, the electrical field caused the acid droplet to spread out widely across the aluminum surface, a phenomenon called “electrowetting” where electric fields change how liquids behave on surfaces. This created larger transparent spots, but the quality suffered. Lower power at 1.5 volts produced smaller, clearer spots but required more patience. The Goldilocks setting turned out to be 2 volts, creating high-quality transparent spots in a reasonable time.
The resulting material was remarkably clear, allowing over 70% of visible light to pass through, nearly as transparent as the glass it was created on. But it had another interesting property: while letting through the light we can see, it blocked more of the invisible near-infrared light (the kind that carries heat). This dual nature could make it valuable for energy-efficient windows that let in light but keep out heat or for specialized optical filters in cameras and sensors.
FESEM (field emission scanning electron microscopy) images of (a) Al metal and anodized samples at 2, 6, and 10 min (TAlOx). Also shown are the (b) magnified 3D AFM scan of Al metal and TAlOx. (c) The nanoporous surface of TAlOx and (d) cross-sectional layers as revealed by FESEM. Click to expand. (Credit: Langmuir)
=======================================================================================
In this process, the metal undergoes several stages, forming different compounds of aluminum with oxygen and hydrogen. Researchers tracked these changes using sophisticated X-ray techniques, watching as ordinary metal evolved into a transparent material.
Perhaps most impressive was how the surface changed. Standard aluminum has a somewhat rough, grainy surface at microscopic levels. But as the transformation progressed, this surface became increasingly smooth, with tiny, randomly scattered pores developing throughout. This smoothness contributes to the material’s clarity and quality.
A Better Overall Product?
The approach offers major advantages over traditional methods. Rather than needing to mask off protected areas with special coatings, the droplet itself creates a natural boundary for the reaction. The electric field contains and controls the process within this tiny chemical workshop. It transforms only exactly what needs changing and leaves everything else untouched.
In addition to drastically reducing chemical waste, scientists say the technique creates a better product. The team found their droplet method produced smoother, more uniform transparent areas than conventional techniques. They believe this happens because the limited amount of acid in the droplet creates a more controlled environment for the transformation, preventing the excessive movement of chemical components that can lead to irregularities.
While commercial transparent oxide production often requires specialized vacuum equipment or complex processing steps, this approach needs only a basic power supply, a platinum wire, and dilute acid which is available in most modest laboratories. This accessibility could democratize the production of specialized optical materials, allowing smaller research groups and companies to innovate without massive infrastructure investments.
Aluminum That’s Transparent — And Greener Too
For electronic device manufacturers, this technique could potentially open new avenues for creating transparent components with less environmental impact. The process doesn’t require specialized equipment, works at room temperature, and uses minimal resources, all attractive features for sustainable manufacturing.
Researchers suggest that the same approach could be applied to other metals to create various transparent metal oxides, expanding the potential applications of this method across different industries. Each metal oxide has unique properties, some might offer better electrical conductivity, others superior hardness or optical characteristics, creating a toolbox of materials for different applications.
While the current research focused on small-scale demonstrations, the technique could potentially be scaled up for industrial applications. Multiple droplets could be precisely positioned to create patterns of transparent areas or the process could be integrated into existing manufacturing workflows to reduce chemical usage.
As consumers and regulators increasingly push for greener manufacturing processes, techniques that minimize chemical usage and waste are becoming more valuable to industry. For everyday consumers, this study might not immediately change the devices in their pockets, but it represents the kind of incremental improvement in manufacturing techniques that collectively make electronics more sustainable and potentially less expensive over time.
From the humble aluminum can to the sophisticated circuitry in our devices, aluminum has long been a workhorse material in our modern world. Now, with nothing more than a droplet of acid and a small electrical current, this common metal can transform into a crystal-clear material with applications we’re just beginning to explore.
Gallium will do that too because of the same reason: ‘likes dissolve likes’. In the case of Gallium you need a slightly higher than room temperature. I heard of a joke where they gave new students Gallium spoons only to have it melt in their hands
Alien slobber?
I spilled some on my ladder and now I can’t find it.
Way cool!! I heard talk in the late 1960s regarding transparent aluminum. He was an ex-military guy.
Yeah but how do we know he didn’t invent the stuff?
Far out, man!
Now that’s amazing.
Where's Al?
Perfect. I came to this article for this comment. Now imagine a Pakistani plane lol.
Is the snake redolent of Istil? If so, it needs wings.
And here I thought transparent aluminum was science fiction.
I was looking for this pic!
“A keyboard!? How quaint.”
Invisibility
Fat girl says to Al : Am I invisible to you?
Al says to fat girl: Possibly from Pluto.
Fat girl says: you say that to my face?
Al says: I’d say it to your back but my car is low on gas
I saw the headline and the comments do NOT disappoint! :-D
Back in the day, “ and that day was Tuesday “ one of my prime reason to get on FR was the comments, sadly much less of a reason meow
Some people are just huge and series😎
Last year there was an article here on FR about making wood transparent.
If this trend catches on people will be bumping into things a lot more.
Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.