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New Nanomaterial Produces Clean Energy Hydrogen Fuel From Seawater
https://scitechdaily.com ^ | September 14, 2021 | By UNIVERSITY OF CENTRAL FLORIDA

Posted on 09/14/2021 7:28:11 AM PDT by Red Badger

Researchers at the University of Central Florida have designed for the first time a nanoscale material that can efficiently split seawater into oxygen and a clean energy fuel — hydrogen.

The material offers the high performance and stability needed for industrial-scale electrolysis, which could produce a clean energy fuel from seawater.

Hydrogen fuel derived from the sea could be an abundant and sustainable alternative to fossil fuels, but the potential power source has been limited by technical challenges, including how to practically harvest it.

Researchers at the University of Central Florida have designed for the first time a nanoscale material that can efficiently split seawater into oxygen and a clean energy fuel — hydrogen. The process of splitting water into hydrogen and oxygen is known as electrolysis and effectively doing it has been a challenge until now.

The stable, and long-lasting nanoscale material to catalyze the reaction, which the UCF team developed, is explained this month in the journal Advanced Materials.

“This development will open a new window for efficiently producing clean hydrogen fuel from seawater,” says Yang Yang, an associate professor in UCF’s NanoScience Technology Center and study co-author.

Hydrogen is a form of renewable energy that—if made cheaper and easier to produce—can have a major role in combating climate change, according to the U.S. Department of Energy.

Hydrogen could be converted into electricity to use in fuel cell technology that generates water as product and makes an overall sustainable energy cycle, Yang says.

How It Works The researchers developed a thin-film material with nanostructures on the surface made of nickel selenide with added, or “doped,” iron and phosphor. This combination offers the high performance and stability that are needed for industrial-scale electrolysis but that has been difficult to achieve because of issues, such as competing reactions, within the system that threaten efficiency.

The new material balances the competing reactions in a way that is low-cost and high-performance, Yang says.

Using their design, the researchers achieved high efficiency and long-term stability for more than 200 hours.

“The seawater electrolysis performance achieved by the dual-doped film far surpasses those of the most recently reported, state-of-the-art electrolysis catalysts and meets the demanding requirements needed for practical application in the industries,” Yang says.

The researcher says the team will work to continue to improve the electrical efficiency of the materials they’ve developed. They are also looking for opportunities and funding to accelerate and help commercialize the work.

Reference: “Dual-Doping and Synergism toward High-Performance Seawater Electrolysis” by Jinfa Chang, Guanzhi Wang, Zhenzhong Yang, Boyang Li, Qi Wang, Ruslan Kuliiev, Nina Orlovskaya, Meng Gu, Yingge Du, Guofeng Wang and Yang Yang, 8 July 2021, Advanced Materials. DOI: 10.1002/adma.202101425

More About The Team

Co-authors included Jinfa Chang, a postdoctoral scholar, and Guanzhi Wang, a doctoral student in materials science engineering, both with UCF’s NanoScience Technology Center; and Ruslan Kuliiev ’20MS, a graduate of UCF’s Master’s in Aerospace Engineering program, and Nina Orlovskaya, an associate professor with UCF’s Department of Mechanical and Aerospace Engineering, and Renewable Energy and Chemical Transformation Cluster.

Yang holds joint appointments in UCF’s NanoScience Technology Center and the Department of Materials Science and Engineering, which is part of the university’s College of Engineering and Computer Science. He is a member of UCF’s Renewable Energy and Chemical Transformation (REACT) Cluster. He also holds a secondary joint-appointment in UCF’s Department of Chemistry. Before joining UCF in 2015, he was a postdoctoral fellow at Rice University and an Alexander von Humboldt Fellow at the University of Erlangen-Nuremberg in Germany. He received his doctorate in materials science from Tsinghua University in China.


TOPICS: Business/Economy; Health/Medicine; Outdoors; Science
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To: Red Badger
Of course, even if 100% efficiency is achieved (impossible, unless the 2nd. Law of Thermodynamics is repealed) it will sill take as much energy to produce the hydrogen as is obtained from burning it.

Then, add to this the myriad of problems that using hydrogen creates:

Heavy and large storage tanks
Embrittlement of metal distribution pipes
Low energy density
Inability to liquify
Leakage due to small molecular size
Very high storage pressures
.
.
.

21 posted on 09/14/2021 8:16:46 AM PDT by norwaypinesavage (Capitalism is what happens when you leave people alone.)
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To: Red Badger

🐙🐌🍻. Making me hungry now dang it.


22 posted on 09/14/2021 8:19:56 AM PDT by rktman (Destroy America from within? Check! WTH? Enlisted USN 1967 to end up with this? 😕)
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To: Maine Mariner

I’m 110% sure you are correct

However, this sounds like a win-win for the eco-whack jobs. Clean energy and by using seawater it will reduce the rise of the oceans which is a byproduct of AGW. /s


23 posted on 09/14/2021 8:22:06 AM PDT by shotgun
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To: ctdonath2

Butt, butt, butt zero carbon. Well except making EVERYTHING to make EVERY component. Other than that, yeah.


24 posted on 09/14/2021 8:22:07 AM PDT by rktman (Destroy America from within? Check! WTH? Enlisted USN 1967 to end up with this? 😕)
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To: norwaypinesavage

Well, all of that is true!

ALL THEY NEED TO DO IS ADD SOME CARBON ATOMS TO THE HYDROGEN ATOMS, HOPEFULLY IN LONG CHAINS AND RINGS, AND THOSE PROBLEMS WILL BE SOLVED!...............


25 posted on 09/14/2021 8:24:32 AM PDT by Red Badger (Homeless veterans camp in the streets while illegal aliens are put up in hotels.....................)
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To: norwaypinesavage

You mean there really is no such thing as a free lunch? drat.


26 posted on 09/14/2021 8:29:32 AM PDT by hinckley buzzard ( Resist the narrative.)
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To: ProtectOurFreedom
"I wish them luck, but it’s a long, tough chemical and mechanical engineering journey from lab-scale to highly reliable, economical, commercial scale."

Agreed. Plus, you will have the environ-weenies and the fossil fuel industry fighting such tech. Then you have the distribution system that would need the gas companies to convert, and who owns the existing pipelines? Plus, are hydrogen fuel cells perfected and economical for vehicles? Real question.

Also, as pointed out above, desalination/filtering plants would have to be built.

27 posted on 09/14/2021 8:35:00 AM PDT by A Navy Vet (USA Birth Certificate - 1787. Death Certificate - 2021. )
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To: Red Badger

How long before the Chicoms steal this technology?
I think the best way for a hydrogen economy is to split seawater to hydrogen and oxygen, but use genetically-engineered kelp plants to create gaseous nodules of hydrogen for harvesting. Use sunlight/photosynthesis.


28 posted on 09/14/2021 8:35:26 AM PDT by Frohickey
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To: Frohickey

Last sentence:

He received his doctorate in materials science from Tsinghua University in China.


29 posted on 09/14/2021 8:37:55 AM PDT by Red Badger (Homeless veterans camp in the streets while illegal aliens are put up in hotels.....................)
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To: shotgun

I saw how the eco-wack jobs in Maine some 20 years or so ago.

They pushed hard for wind power. And anyone who opposed wind projects were reactionaries under the thumb of the fossil fuel industry.

So, wind mills started to be built-some were fairly large projects funded with private investment funds. And yes you guessed it; the eco-wack jobs started to complain about these projects. It is a no-win position with these leftists.


30 posted on 09/14/2021 8:40:00 AM PDT by Maine Mariner
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To: z3n
Good questions, I don't know the answers. With all my years in CA, I've always heard how expensive they are to build. There's one just south of Huntington Beach, CA and it's about the size of a small oil refinery. However, with today's mechanical and tech advances, they might be more cost effective. Read my post above about the distribution problem and those who would fight such a change to hydrogen.

I also wonder why hydrogen would be better than natural gas to your stove and other applications. I also asked above, are hydrogen fuel cells for vehicles safe and economical? And what about petroleum by-products that are used in countless every day products. You probably have dozens of products in your own home. Think plastic to start.

31 posted on 09/14/2021 8:48:53 AM PDT by A Navy Vet (USA Birth Certificate - 1787. Death Certificate - 2021. )
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To: Aevery_Freeman

No, they’ll capture the O2. Hospitals need it for all the ventilators for Covid-x patients.

And of course they have competition for that resource from Elon Musk who needs LOX to keep the rockets flying.


32 posted on 09/14/2021 8:52:48 AM PDT by AFreeBird
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To: Maine Mariner

Read the names.... While the rest of the world is producing STEM geniuses the dumbed down brainwashed clowns with “American” names are going to college to become environmental lawyers and gender queer studies.


33 posted on 09/14/2021 8:53:08 AM PDT by Organic Panic (Democrats. Memories as short as Joe Biden's eyes.)
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To: z3n
Magnesium has been commercially extracted from seawater via electrolysis since about 1940. This is the primary source of magnesium worldwide.

You're certainly correct that seawater has a myriad of mineral salts in it but AFAIK magnesium metal and sodium chloride salt via evaporation are about the only inorganics commercially obtained from seawater. Other inorganics are not economically recoverable, again AFAIK. I've been away from the state of the art in this for quite a time.

Trivia! The gargantuan Dow Chemical chemical complex in Freeport, TX started up in 1940. Not one but two duplicate complexes were built in 18 months including sea walls and a 5-mile barge canal to Plant B. It had the same priorities for funding and resources as the Manhattan Project, which led to the nuclear bomb. Plant A is on the coast adjacent to the harbor and Plant B is about 5 miles inland. Plant B was insurance as it was out of range of deck guns on WWII German submarines. Primary products were magnesium, chlorine, sodium hydroxide and epoxy. Magnesium for flares and incendiaries, chlorine and caustic for explosives and epoxy for Bakelite (ex. aircraft dash panels).

34 posted on 09/14/2021 8:58:53 AM PDT by Hootowl99
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To: Organic Panic

I just retired from teaching for over 30 years at the Maritime College in Maine. We graduate engineers with plenty of hands-on practical training. Also, we graduate students who major in international business and logistics, with an emphasis on logistics and supply chain management. The students in our hands-on programs are usually employed before they graduate or within 30 days after.


35 posted on 09/14/2021 11:08:01 AM PDT by Maine Mariner
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To: A Navy Vet

“Then there is the problem with the hydrogen fuel cells in vehicles. I’m not sure if that has been perfected as yet.”

An on-demand system would nix the fuel cell.


36 posted on 09/14/2021 11:08:55 AM PDT by LastDayz (A blunt and brazen Texan. I will not be assimilated.)
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To: Red Badger

How much power does it take to accomplish the split? Will the cost be prohibitive?


37 posted on 09/14/2021 11:20:03 AM PDT by JimRed (TERM LIMITS, NOW! Militia to the border! TRUTH is the new HATE SPEECH.)
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To: Red Badger

Ok, from what I’m reading they built a better electrolysis plate. However, the energy deficit will be the larger problem. You have to input energy to run electrolysis. Where’s that energy come from?


38 posted on 09/14/2021 11:22:39 AM PDT by Lazamataz (I feel like it is 1937 Germany, and my last name is Feinberg.)
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To: rktman
"Butt, butt, butt zero carbon. Well except making EVERYTHING to make EVERY component. Other than that, yeah."

That is what the environ-weenies and politicians never realize or ignore.

39 posted on 09/14/2021 11:24:49 AM PDT by A Navy Vet (USA Birth Certificate - 1787. Death Certificate - 2021. )
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To: Lazamataz

E-Cat......................


40 posted on 09/14/2021 11:25:03 AM PDT by Red Badger (Homeless veterans camp in the streets while illegal aliens are put up in hotels.....................)
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