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Grad student discovers unique valleytronics properties of tungsten disulfide monolayer film
phys.org ^ | December 3, 2015 | Denis Paiste & Provided by: Massachusetts Institute of Technology

Posted on 12/03/2015 2:11:31 PM PST by Red Badger

Researchers at the Gedik Lab at MIT use strong ultrafast laser pulses to stimulate changes in material, followed by a weaker probe laser pulse after some time delay to monitor the changes with femtosecond time resolution. Tungsten (W) atoms are black, and sulfur (S) atoms are yellow. Credit: Edbert Jarvis Sie

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Monolayer films of tungsten disulfide, just three atoms thick, have unique electronic valleys which can be manipulated with laser light. This finding, by MIT physics graduate student Edbert Jarvis Sie, Associate Professor Nuh Gedik, and colleagues, was significant enough to warrant placement on the cover of Nature Materials earlier this year.

The cover illustrates a tornado-like whorl of light, lifting an electronic band in the material to a higher energy state, which widens the band gap in the material. This widening is known as the optical Stark effect. The researchers, under senior author Nuh Gedik, the Lawrence C. (1944) and Sarah W. Biedenharn Career Development Associate Professor of Physics at MIT, found that applying circularly polarized laser light lifted the energy in one valley while leaving the energy in the other valley unaffected. "There are two valleys. If we switch the laser polarization, the effect switches to the other valley," Sie says. Gedik spoke about his group's research on topological insulators at the Materials Day Symposium, on Oct. 14, in Kresge Auditorium.

"In materials, electrons travelling in different directions experience different scattering potential with the atoms. This establishes an energy landscape as a function of electron's momentum, which can form a local minimum that we call a valley," Sie explains. "The phenomenon of the valleys only occurs in these extremely thin, monolayer forms of the tungsten sulfur compound, not in its bulk form. These valleys normally have the same energy. But as we apply this circularly polarized light, we can lift the energy of one valley relative to the other."

Seeking chiral edge state

Sie is continuing the research by leading an effort to demonstrate a phenomenon predicted by MIT assistant professor of physics Liang Fu that electrons at the boundary of the laser spot will travel clockwise or counterclockwise depending on their spin and the light polarization, thus creating the so-called chiral edge state. "Research is currently ongoing in order to establish this new phase of matter and to observe it," Sie says. The chiral edge state is predicted to occur in the valley opposite to the one whose bandgap is affected by the circularly polarized light.

MIT physics graduate student Edbert Sie works in the Gedik Lab to innovate optical control of electrons in monolayer materials — and possible new methods for information processing, such as valleytronics. Credit: Denis Paiste/Materials Processing Center ========================================================================================================================================

This valley degree of freedom, or valley index, has a potential to be used for carrying information like in a computer. Transistors nowadays are reaching a fundamental size limit that is either difficult or too expensive to overcome, and monolayer materials like tungsten disulfide may have the capability to carry the next generation of electronics, Sie suggests.

Previous approaches to creating topological insulators involved layering materials such as mercury telluride with cadmium telluride or alloying a material such as thallium bismuth sulfide with an additional element such as selenium, Sie explains. "In our new approach that we are trying to do, we don't need to do any sandwiching or putting additional elements," Sie says. "We take this normal material, a semiconductor, and we just shine light to turn it into a topological insulator."

On-off switch

"By turning on the laser light, we can have a topological insulator; by turning it off, we can have back our semiconductor from the same piece of material. Because this material has a valley index, which is unique, then we can have this sort of valley-flavored topological insulator," he explains.

Sie, 29, who is from Indonesia, is a fifth-year graduate student in physics and expects to graduate in fall 2017. He earned his bachelor's degree in physics at Nanyang Technological University in Singapore. He was a silver medalist in the 2004 International Physics Olympiad, held that year in South Korea. Since his early years, Sie also enjoyed drawing and painting, and earlier considered becoming an artist. That interest came into play when he came up with a sketch for the image that eventually became the cover for his Nature Materials article.

Explore further: Topological insulators: Persuading light to mix it up with matter

More information: Edbert J. Sie et al. Valley-selective optical Stark effect in monolayer WS2, Nature Materials (2014). DOI: 10.1038/nmat4156

Journal reference: Nature Materials


TOPICS: Business/Economy; Computers/Internet; Health/Medicine; Science
KEYWORDS: electronics; memory; tech; tungsten
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To: Red Badger

Agreed. That volleyball thingy...


21 posted on 12/03/2015 2:42:36 PM PST by dhs12345
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To: Red Badger

Pay me enough and I’ll make this article into a comic book.

You’ll laugh; you’ll cry a little too, but you’ll never look at things the same way again.


22 posted on 12/03/2015 2:43:54 PM PST by tsomer
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To: Red Badger
I understood "It's basically a possible way to store".

After that you lost me.

23 posted on 12/03/2015 2:45:02 PM PST by Lazamataz ( If they try firearm confiscation or gun registration, I go ballistic.)
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To: Lazamataz

I’ll just boil it down to this, for you, Laz:

More porn. Faster porn....................


24 posted on 12/03/2015 2:49:35 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger
electrons at the boundary of the laser spot will travel clockwise or counterclockwise depending on their spin

So if they are spinning clockwise, they'll travel clockwise? And vice-versa? What's so hard about that?

25 posted on 12/03/2015 2:50:55 PM PST by ProtectOurFreedom (For those who understand, no explanation is needed. For those who do not, no explanation is possible)
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To: beaversmom

It’s because of the amount of studying they do. It is very much part of their culture, immense pressure to do well so they study hard.

When it comes to competitive efficiency in business, being able to make fast decisions, they don’t do so well. Endless chains of approvals, it takes forever to get agreements.


26 posted on 12/03/2015 2:51:31 PM PST by fuzzylogic (welfare state = sharing consequences of poor moral choices among everybody)
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To: Red Badger
Non-volatile storage like a high density DVD? How long does the “valley” hold its state?
27 posted on 12/03/2015 2:51:37 PM PST by dhs12345
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To: Red Badger

Ok thanks, that was understandable.


28 posted on 12/03/2015 2:52:32 PM PST by Lazamataz ( If they try firearm confiscation or gun registration, I go ballistic.)
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To: dhs12345

Unknown. More research, of course.................


29 posted on 12/03/2015 2:54:27 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: beaversmom

I’ve visited Nanyang and have done some courses for faculty there. Impressive institution.


30 posted on 12/03/2015 2:59:35 PM PST by NewHampshireDuo
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To: fuzzylogic
It’s because of the amount of studying they do. It is very much part of their culture, immense pressure to do well so they study hard. I think you are correct as far as math and science. I saw that with one of my kid's Oriental friends from a few years back. He was quite smart and I think his parents were quite strict as far his homework...even over the summer. I wonder why a lot of them are so good at drawing/art? That was another thing I noticed.
31 posted on 12/03/2015 3:01:48 PM PST by beaversmom
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To: Red Badger

Stability is important. Especially across temperature and environmental conditions.


32 posted on 12/03/2015 3:06:58 PM PST by dhs12345
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To: Red Badger

I didnt understand that to be about memory, but electron movement, sort of like a buss, with insulation possible between, so smaller devices can have flow and reduced size to get the same effect from a much smaller device


33 posted on 12/03/2015 4:07:13 PM PST by RaceBannon (Rom 5:8 But God commendeth his love toward us, in that, while we were yet sinners, Christ died for)
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To: RaceBannon
This valley degree of freedom, or valley index, has a potential to be used for carrying information like in a computer. Transistors nowadays are reaching a fundamental size limit that is either difficult or too expensive to overcome, and monolayer materials like tungsten disulfide may have the capability to carry the next generation of electronics, Sie suggests.
34 posted on 12/04/2015 6:19:32 AM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: ProtectOurFreedom

One of the principles of a possible quantum computer would be to utilize the electron spin direction as a 1 or a 0 for massive data manipulation...........................


35 posted on 12/04/2015 6:22:52 AM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: beaversmom

I had lunch with a friend of mine from Taiwan today. They are trying to shield their 11 year old daughter from some of the pressure. But they say the peer pressure from other Asian kids in the school is so intense that the parents don’t even have to apply the pressure! This is a heavily Chinese area in Fremont, CA.


36 posted on 12/04/2015 4:56:35 PM PST by ProtectOurFreedom (For those who understand, no explanation is needed. For those who do not, no explanation is possible)
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To: ProtectOurFreedom

Definitely pluses and minues to that way of thinking. Hard on kids, though, that can’t measure up.


37 posted on 12/04/2015 8:20:12 PM PST by beaversmom
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To: beaversmom

Yes, extremely hard. The kids seem to miss out on a lot of childhood. Worst case they commit suicide.


38 posted on 12/05/2015 4:41:42 AM PST by ProtectOurFreedom (For those who understand, no explanation is needed. For those who do not, no explanation is possible)
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