Posted on 02/11/2015 5:10:39 AM PST by thackney
Ectric cars are quick and quiet, with a range more than long enough for most commutes. If you want a car with extremely fast acceleration, the Tesla Model S is hard to beat. And, of course, electric vehicles avoid the pollution associated with conventional cars, including emissions of carbon dioxide from burning gasoline. Yet they account for a tiny fraction of automotive sales, mainly because the batteries that propel them are expensive and need to be recharged frequently.
A better battery could change everything. But while countless breakthroughs have been announced over the last decade, time and again these advances have failed to translate into commercial batteries with anything like the promised improvements in cost and energy storage. Some well-funded startups, most notably A123 Systems, began with bold claims but failed to deliver (see “What Happened to A123?”).
The Powerhouse, a new book by journalist Steve LeVine, chronicles the story behind one of the most dramatic battery announcements of recent years and explains how it came to nothing (see “The Sad Story of the Battery Breakthrough that Proved Too Good to Be True”). The announcement was made in February 2012, at a conference in Washington, D.C., where a crowd of researchers, entrepreneurs, and investors had come to hear the likes of Bill Gates and Bill Clinton expound on the importance of new energy technology—and also to tap into one of the newest funding sources in Washington, the Advanced Research Projects Agency for Energy, or ARPA-E. Founded in 2009, ARPA-E had been tasked with identifying potentially transformational research. The head of that agency, Arun Majumdar, was ready to unveil one of its first major successes: a battery cell, developed by the startup Envia, that could store twice as much energy as a conventional one. The cost of a battery that could take a car from Washington to New York without recharging, Majumdar said, would fall from $30,000 to $15,000. Electric cars would become far more affordable and practical (see “A Big Jump in Battery Capacity”).
Within months, GM licensed the technology and signed an agreement to support its development, gaining the right to use any resulting batteries. The deal was potentially worth hundreds of millions of dollars to Envia, LeVine writes. But soon Envia was getting frustrated messages from GM engineers who couldn’t reproduce the startup’s results. The year after the announcement, the deal was scuttled. Envia’s impressive battery had been a fluke.
LeVine’s account of Envia’s work shows why major progress in batteries is so hard to achieve and why startups that promise world-changing breakthroughs have struggled. Over the last decade we’ve seen remarkable improvements in this industry, but they’ve come largely from established companies steadily making small advances.
Envia’s cell was a new type of lithium-ion battery. Invented in the late 1970s and early 1980s and commercialized in the 1990s, these batteries generate electrical current when lithium ions shuttle between two electrodes. Light but powerful, they have transformed portable electronics. Their use in electric cars, however, is recent. In the 1990s, GM used cheaper lead-acid batteries for its electric EV-1; each battery weighed a bulky 600 kilograms and delivered only 55 to 95 miles before it needed to be recharged. When Tesla Motors introduced one of the first lithium-ion-powered electric cars in 2008, it could go 250 miles on a charge, roughly three times farther than the EV-1. But the vehicle cost over $100,000, in large part because the batteries were so expensive. To cut costs, the lithium-ion-powered electric cars made today by companies such as Nissan and GM use small battery packs with a range of less than 100 miles.LeVine’s account of Envia’s work shows why major progress in batteries is so hard to achieve and why startups that promise world-changing breakthroughs have struggled. Over the last decade we’ve seen remarkable improvements in this industry, but they’ve come largely from established companies steadily making small advances.
Envia’s cell was a new type of lithium-ion battery. Invented in the late 1970s and early 1980s and commercialized in the 1990s, these batteries generate electrical current when lithium ions shuttle between two electrodes. Light but powerful, they have transformed portable electronics. Their use in electric cars, however, is recent. In the 1990s, GM used cheaper lead-acid batteries for its electric EV-1; each battery weighed a bulky 600 kilograms and delivered only 55 to 95 miles before it needed to be recharged. When Tesla Motors introduced one of the first lithium-ion-powered electric cars in 2008, it could go 250 miles on a charge, roughly three times farther than the EV-1. But the vehicle cost over $100,000, in large part because the batteries were so expensive. To cut costs, the lithium-ion-powered electric cars made today by companies such as Nissan and GM use small battery packs with a range of less than 100 miles.
One difficult thing about developing better batteries is that the technology is still poorly understood. Changing one part of a battery—say, by introducing a new electrode—can produce unforeseen problems, some of which can’t be detected without years of testing. To achieve the kinds of advances venture capitalists and ARPA-E look for, Envia incorporated not just one but two experimental electrode materials.
LeVine describes what went wrong. In 2006 Envia had licensed a promising material developed by researchers at Argonne National Laboratory. Subsequently, a major problem was discovered. The problem—which one battery company executive called a “doom factor”—was that over time, the voltage at which the battery operated changed in ways that made it unusable. Argonne researchers investigated the problem and found no ready answer. They didn’t understand the basic chemistry and physics of the material well enough to grasp precisely what was going wrong, let alone fix it, LeVine writes.
With its experimental material for the opposite electrode, this one based on silicon, Envia faced another challenge. Researchers had seemingly solved the major problem with silicon electrodes—their tendency to fall apart. But the solution required impractical manufacturing techniques.
When Envia made its announcement in 2012, it seemed to have figured out how to make both these experimental materials work. It developed a version of the silicon electrode that could be manufactured more cheaply. And through trial and error it had stumbled upon a combination of coatings that stabilized the voltage of the Argonne material. Envia cofounder Sujeet Kumar “understood that the answer was a composite of coatings,” LeVine writes. “But he still didn’t know what the composite was arresting or why it succeeded in doing so.” Since Envia was a startup with limited funds, he “didn’t have the instruments that could figure it out.” But once it became obvious that the results Envia had reported for its battery couldn’t be reproduced, understanding the problem became crucial. Even tiny changes to the composition of a material can have a significant impact on performance, so for all Envia knew, its record-setting battery worked because of a contaminant in a batch of material from one of its suppliers.
The story of Envia stands in sharp contrast to what’s turned out to be the most successful recent effort to cut the price of batteries and improve their performance. This success hasn’t come from a breakthrough but from the close partnership between Tesla Motors and the major battery cell supplier Panasonic. Since 2008, the cost of Tesla’s battery packs has been cut approximately in half, while the storage capacity has increased by about 60 percent. Tesla didn’t attempt to radically change the chemistry or materials in lithium-ion batteries; rather, it made incremental engineering and manufacturing improvements. It also worked closely with Panasonic to tweak the chemistry of existing battery materials according to the precise needs of its cars.
Tesla claims that it is on track to produce a $35,000 electric car with a roughly 200-mile range by 2017—a feat that’s equivalent to what GM hoped to achieve with Envia’s new battery. The company anticipates selling hundreds of thousands of these electric cars a year, which would be a big leap from the tens of thousands it sells now. Yet for electric cars to account for a significant portion of the roughly 60 million cars sold each year around the world, batteries will probably need to get considerably better. After all, 200 miles is far short of the 350-plus miles people are used to driving on a tank of gasoline, and $35,000 is still quite a bit more than the $15,000 price of many small gas-powered cars.
How will we close the gap? There is probably still plenty of room to improve lithium-ion batteries, though it’s hard to imagine that Tesla’s success with minor changes to battery chemistry will continue indefinitely. At some point, radical changes such as the ones Envia envisioned may be needed. But the lesson from the Envia fiasco is that such changes must be closely integrated with manufacturing and engineering expertise.
That approach is already yielding promising results with the Argonne material that Envia licensed. Envia’s battery operated at high voltages to achieve high levels of energy storage. Now battery manufacturers are finding that using more modest voltage levels can significantly increase energy storage without the problems that troubled Envia. Meanwhile, battery researchers are publishing papers that show how trace amounts of additives change the behavior of the materials, making it possible to edge up the voltage and energy storage. The key is to combine research that illuminates details about the chemistry and physics of batteries with the expertise that battery manufacturers have gained in making practical products.
It’s an industry in which it’s very difficult for a startup, however enticing its technology, to go it alone. Andy Chu, a former executive at A123 Systems, which went bankrupt in 2012, recently told me why large companies dominate the battery industry. “Energy storage is a game played by big players because there are so many things that can go wrong in a battery,” he said. “I hope startups are successful. But you can look at the history over the past few years, and it’s not been good.”
Yep, thats basic physics. You cannot get more out of something than you put in it.
Driving range is just one problem with electric cars. Recharging time is also an issue for consumers. Instead of a 10 minute fill up at a gas station, electric cars would require hours of recharging. This might not be a problem if you are driving to work and can recharge there, but consider driving your electric car on vacation, making deliveries or even a weekend trip. Long recharge times could be a nightmare on the road. Imagine pulling into a recharge station and waiting hours in line for your hours long recharge.
Good meters owned by the idiots at Danaher Corp.
I've wondered for a while if there was a market for a small trailer mounted generator for those long trips.
Anyone who ever watched the original Star Trek series knows that the early starship warp drive reactors were powered by lithium crystals. The series was set in the 23rd century, so we still have to wait about 200 years until lithium crystals become common as a power source on starships. This is not to say the crystals will not be used earlier in other systems.
Flavor of the day, right?
lol
My flashlight is powered by the 18650 battery.
I have been told that the Tesla is powered by the very same battery, but several hundred of them.
If they can put a man on the moon, why can't they invent a cheap, sustainable car battery with a 500+ mile-range that can also go faster than the speed of light?
Zactly.....
Attach a lightening rod to the roof of a car to catch lightening bolts and somehow convert that energy to usable energy, connect to the drive train and you'd have almost free energy.
I suppose I'd better tell you, I'm not serious about that, lest you think I'm a liberal.
It's magic!!
I don’t know a whole lot about electric cars, but have read that ghere is a move to stadardize removeable batteries that can be changed in minutes ar a charging station. I would expect a noticable fee for such a service.
Not the same, but similar.
Tesla: thousands of cells
In contrast to every other automaker, which use specialized large format Li-Ion cells, Tesla’s battery pack is made up of thousands of inexpensive commodity cells similar to those found in laptops.
Unlike automotive cells, these cells are produced in the billions, subject to the fierce competitive pressures that are a signature characteristic of the computer and consumer electronics industries.
Even including the overhead of the pack enclosure, connections between cells in modules (and modules in the pack), sensors, and circuitry, Tesla likely has lower pack costs than any other maker of plug-in electric cars.
Simplifying a cheap cell
But for the Model S, Tesla redesigned what was already a relatively simple cell to be much less complex, and to have a much lower manufacturing cost—largely by removing expensive safety systems built into each individual cell.
When used as a laptop battery, each cells requires a safety mechanisms to prevent fires. But in a large, electronically-controlled, liquid-cooled battery pack like the one used in the Tesla Model S, having certain safety features on each cell would be redundant.
In this case, the company’s cell design eliminates the relatively complicated battery cap of the commercial cell, and replaces it with a simple aluminum disk.
Intumescent goo
Having radically simplified the cells, Tesla then designed simple and inexpensive fireproofing systems into its battery pack. Among many innovations, Tesla appears to have incorporated a form of intumescent goo that it sprays onto the interior of the pack to aid in fireproofing.
When exposed to heat, a chemical reaction occurs in the goo that helps cool the heat source, while simultaneously forming a fireproof barrier to protect the rest of the pack.
I believe Scotty said they wer “Di-Lithium Crystals” Captain. And sheez, they were always on verge of blowing up or something.
Liberals are so accustomed to breaking mankind’s laws they believe they should be able to break natural law with the same ease.
Quick change battery packs to swap out.
Capacitors. Really big capacitors!
Txchnologist, an online magazine sponsored by General Electric, talked to team member and aerospace engineering PH.D. candidate Ross Cortez, he said “The fusion fuel we’re focusing on is deuterium [a stable isotope of hydrogen] and Li6 [a stable isotope of the metal lithium] in a crystal structure.”
“That’s basically dilithium crystals we’re using,” he said.
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