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Invisible membrane sorts molecules
Cosmos Online ^ | 2/16/07

Posted on 02/15/2007 9:38:19 PM PST by LibWhacker

NEW YORK: A newly designed porous membrane, so thin that it's invisible edge-on, might revolutionise the way doctors and scientists manipulate objects as small as molecules.

The 50-atom thick filter can withstand surprisingly high pressures and may be a key to better separation of blood proteins for dialysis patients, speeding ion exchange in fuel cells and purifying air and water at the nanoscopic level.

"It's amazing, we have a material as thin as some of the molecules it's sorting, and riddled with holes - but it can withstand enough pressure to make real-world nano-filtering a practical reality," said Christopher Striemer of the University of Rochester in New York, co-creator of the membrane.

Details of the membrane, which is more than 4,000 times thinner than a human hair - thousands of times thinner than similar filters in use today - are published this week in the British journal Nature. The membrane is a 15-nanometer-thick slice of the same silicon that's used every day in computer-chip manufacturing.

Striemer developed the design while searching for a way to better understand how silicon crystalises when heated. He used such a thin piece of silicon because it would allow him to view the resulting crystal structures with an electron microscope.

As parts of the silicon contracted into crystals, Striemer noticed that holes opened up in their wake. He and colleagues at the University of Rochester realised that - since the membrane's holes were only nanometers in size - it might separate objects as small as proteins much more effectively than existing techniques.

Current molecular-level filters use a polymer-based design that is a jumble of holes and tunnels. The sizes of holes in the polymer vary greatly, and since its 'holes' are really convoluted tunnels through the material, they require much more time for proteins to pass through, and they are prone to clogging.

To test the membrane, the researchers placed a solution of two blood proteins, albumin and IgG, behind the membrane and forced it gently through the nanoscopic holes. In just over six minutes, the albumin had passed through, but the larger IgG protein was stopped. And remarkably, the 50-atom thickness could hold back 10 tonnes per square metre of pressure.

The Rochester team also found a way for the nano-filter to carry a fixed charge, effectively making the hole 'smaller' for molecules of a certain charge than for others. Their membrane can quickly and easily separate molecules by their size and their charge - a serious boon for fuel cell researchers, who wish to move only certain ions from one part of a fuel cell to another.

The Rochester group also foresees many applications for the membrane in medicine, including improved separation of blood proteins for dialysis patients and the nanoscale purification of air and water in hospitals.


TOPICS: Miscellaneous; Technical
KEYWORDS: invisible; membrane; molecules; proteins; sorts

1 posted on 02/15/2007 9:38:21 PM PST by LibWhacker
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To: b_sharp; neutrality; anguish; SeaLion; Fractal Trader; grjr21; bitt; KevinDavis; Momaw Nadon; ...
FutureTechPing!
An emergent technologies list covering biomedical
research, fusion power, nanotech, AI robotics, and
other related fields. FReepmail to join or drop.

2 posted on 02/15/2007 9:43:54 PM PST by AntiGuv ("..I do things for political expediency.." - Sen. John McCain on FOX News)
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To: LibWhacker
Striemer developed the design while searching for a way to better understand how silicon crystalises when heated. He used such a thin piece of silicon because it would allow him to view the resulting crystal structures with an electron microscope.

Serendipity.

3 posted on 02/15/2007 9:44:08 PM PST by Moonman62 (The issue of whether cheap labor makes America great should have been settled by the Civil War.)
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To: LibWhacker

Really cool technology!


4 posted on 02/15/2007 9:46:09 PM PST by MarineBrat (My wife and I took an AIDS vaccination that the Church offers.)
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To: LibWhacker
F'n A, Batman!

If someone can find a nifty scientific use for this (I am thinking of the impact that PCR had) do I smell a Nobel in the offing?

Full Disclosure: even if not, when is their IPO? ;-)

Cheers!

5 posted on 02/15/2007 9:59:52 PM PST by grey_whiskers (The opinions are solely those of the author and are subject to change without notice.)
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To: AntiGuv
Here's how that work fits in with other work using charge this past week.
6 posted on 02/15/2007 10:17:58 PM PST by ckilmer
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To: AntiGuv
Here's how that work fits in with other work using charge this past week.
7 posted on 02/15/2007 10:18:07 PM PST by ckilmer
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To: grey_whiskers
If someone can find a nifty scientific use for this (I am thinking of the impact that PCR had) do I smell a Nobel in the offing?

Yup, I was thinking the same thing. The number of applications seems almost unlimited. For instance, as I understand the problem, the big holdup on implantable insulin pumps is a seemingly insurmountable problem with the filters clogging up. So a discovery like this could change the lives of millions of people in one fell swoop.

8 posted on 02/15/2007 10:32:10 PM PST by LibWhacker
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To: SunkenCiv; LibWhacker
FYI.

Could be an analogy here for smaller forms of energy/matter. I've always visualized the barrier between the quantum and pre-energy as consisting of some sort of membrane.

(Sorry for the off-topic!)

9 posted on 02/15/2007 10:38:36 PM PST by Eastbound
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To: Eastbound

It makes great coffee, too. ;') Depending on durability and stuff, it could wind up useful for fuel cell construction, or reverse osmosis.


10 posted on 02/15/2007 11:49:04 PM PST by SunkenCiv (I last updated my profile on Thursday, February 15, 2007. https://secure.freerepublic.com/donate/)
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To: SunkenCiv

How about cigarette filters? Keep all those carcinagens and stuff from going down the old windpipe.


11 posted on 02/16/2007 12:09:47 AM PST by Eastbound
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To: AntiGuv

thanks for the ping


12 posted on 02/16/2007 12:12:16 AM PST by Kevmo (The first labor of Huntercles: Defeating the 3-headed RINO)
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To: LibWhacker
"For instance, as I understand the problem, the big holdup on implantable insulin pumps is a seemingly insurmountable problem with the filters clogging up."

This gizmo is unlikely to have any effect on that problem. The reason filters used in the body clog up is because the body builds biofilms over them. what is needed is to find a material that is not susceptible to cell growth.

13 posted on 02/16/2007 3:31:33 AM PST by Wonder Warthog (The Hog of Steel-NRA)
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To: AntiGuv
"Current molecular-level filters use a polymer-based design that is a jumble of holes and tunnels. The sizes of holes in the polymer vary greatly, and since its 'holes' are really convoluted tunnels through the material, they require much more time for proteins to pass through, and they are prone to clogging."

Well, except for "track-etch" filters. These use a polycarbonate film, which is "zapped" alpha particles. The ionized "tracks" through the membrane are then exposed to an "etching" chemical, which selectively attacks the ionized sites--yielding a nice little round tunnel wherever an alpha particle hits. Very consistent pore size and shape.

14 posted on 02/16/2007 3:34:38 AM PST by Wonder Warthog (The Hog of Steel-NRA)
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To: Wonder Warthog

Ooohhhhhhhhhh... (***Big lightbulb goes on***)... Thanks for that information, WW! I didn't realize that THAT was the problem. It's a bit more complicated than I imagined.


15 posted on 02/16/2007 12:03:39 PM PST by LibWhacker
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To: grey_whiskers

check out their webpage: www.simpore.com


16 posted on 02/20/2007 7:25:25 PM PST by memMan
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To: LibWhacker

U of R. Meliora, baby!


17 posted on 02/20/2007 7:29:47 PM PST by CaptRon (Pedecaris alive or Raisuli dead)
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To: memMan
check out their webpage: www.simpore.com

Thanks, dude. Bookmarked.

Cheers!

18 posted on 02/20/2007 10:21:58 PM PST by grey_whiskers (The opinions are solely those of the author and are subject to change without notice.)
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