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Why is faith a prerequisite for the sacraments?
Sacraments are not magic. A sacrament can be effective only if one understands and accepts it in faith. Sacraments not only presuppose faith, they also strengthen it and give expression to it.
Jesus commissioned the apostles first to make people disciples through their preaching, in other words, to awaken their faith and only then to baptize them. There are two things, therefore, that we receive from the Church: faith and the sacraments. Even today someone becomes a Christian, not through a mere ritual or by being listed in a register, but rather through acceptance of the true faith. We receive the true faith from the Church. She vouches for it. Because the Church's faith is expressed in the liturgy, no sacramental ritual can be changed or manipulated at the discretion of an individual minister or a congregation.
If a sacrament is administered by someone who is unworthy, does it fail to have its effect?
No. The sacraments are effective on the basis of the sacramental action that is carried out (ex opere operato), in other words, independently of the moral conduct or spiritual outlook of the minister. It is enough for him to intend to do what the Church does.
By all means, ministers of the sacraments ought to live an exemplary life. But the sacraments take effect, not because of the holiness of their ministers, but rather because Christ himself is at work in them. In any case, he respects our freedom when we receive the sacraments. That is why they have a positive effect only if we rely on Christ. (YOUCAT questions 177-178)
Dig Deeper: CCC section (1122-1128) and other references here.
Part 2: The Celebration of the Christian Mystery (1066 - 1690)
Section 1: The Sacramental Economy (1076 - 1209)
Chapter 1: The Paschal Mystery in the Age of the Church (1077 - 1134)
Article 2: The Paschal Mystery in the Church's Sacraments (1113 - 1134)
III. THE SACRAMENTS OF FAITH ⇡
Christ sent his apostles so that "repentance and forgiveness of sins should be preached in his name to all nations."41 "Go therefore and make disciples of all nations, baptizing them in the name of the Father and of the Son and of the Holy Spirit."42 The mission to baptize, and so the sacramental mission, is implied in the mission to evangelize, because the sacrament is prepared for by the word of God and by the faith which is assent to this word: The People of God is formed into one in the first place by the Word of the living God. ... The preaching of the Word is required for the sacramental ministry itself, since the sacraments are sacraments of faith, drawing their origin and nourishment from the Word.43
41.
42.
43.
PO 4 §§ 1,2.
"The purpose of the sacraments is to sanctify men, to build up the Body of Christ and, finally, to give worship to God. Because they are signs they also instruct. They not only presuppose faith, but by words and objects they also nourish, strengthen, and express it. That is why they are called 'sacraments of faith.'"44
44.
SC 59.
The Church's faith precedes the faith of the believer who is invited to adhere to it. When the Church celebrates the sacraments, she confesses the faith received from the apostles whence the ancient saying: lex orandi, lex credendi (or: legem credendi lex statuat supplicandi, according to Prosper of Aquitaine [5th cent.]).45 The law of prayer is the law of faith: the Church believes as she prays. Liturgy is a constitutive element of the holy and living Tradition.46
45.
Ep. 8.
46.
Cf. DV 8.
For this reason no sacramental rite may be modified or manipulated at the will of the minister or the community. Even the supreme authority in the Church may not change the liturgy arbitrarily, but only in the obedience of faith and with religious respect for the mystery of the liturgy.
Likewise, since the sacraments express and develop the communion of faith in the Church, the lex orandi is one of the essential criteria of the dialogue that seeks to restore the unity of Christians.47
47.
Cf. UR 2; 15.
IV. THE SACRAMENTS OF SALVATION ⇡
Celebrated worthily in faith, the sacraments confer the grace that they signify.48 They are efficacious because in them Christ himself is at work: it is he who baptizes, he who acts in his sacraments in order to communicate the grace that each sacrament signifies. The Father always hears the prayer of his Son's Church which, in the epiclesis of each sacrament, expresses her faith in the power of the Spirit. As fire transforms into itself everything it touches, so the Holy Spirit transforms into the divine life whatever is subjected to his power.
48.
Cf. Council of Trent (1547): DS 1605; DS 1606.
This is the meaning of the Church's affirmation49 that the sacraments act ex opere operato (literally: "by the very fact of the action's being performed"), i.e., by virtue of the saving work of Christ, accomplished once for all. It follows that "the sacrament is not wrought by the righteousness of either the celebrant or the recipient, but by the power of God."50 From the moment that a sacrament is celebrated in accordance with the intention of the Church, the power of Christ and his Spirit acts in and through it, independently of the personal holiness of the minister. Nevertheless, the fruits of the sacraments also depend on the disposition of the one who receives them.
49.
Cf. Council of Trent (1547): DS 1608.
50.
St. Thomas Aquinas, STh III, 68,8.