In 449 Pope Leo the Great wrote his Tome against Eutyches, who taught that Jesus Christ had only one nature, not two. (This was the heresy of monophysitism.) In the Tome, which the Council of Chalcedon accepted as the authentic Catholic teaching on Christ, he quotes 1 Timothy 2:5 as the authentic Catholic doctrine: "Hence, as was suitable for the alleviation of our distress, one and the same mediator between God and men, himself man, Christ Jesus, was both mortal and immortal under different.aspects."These quotations from official Catholic documents give unambiguous proof that the Church believes Jesus Christ and no other is the one mediator between sinful humanity and the righteous God
The fifth session of the Council of Trent (1546) laid out the belief in Jesus the one true mediator as the norm of Catholic faith: "[Original sin cannot be] taken away through the powers of human nature or through a remedy other than the merit of the one mediator, our Lord Jesus Christ, who reconciled us to God in his blood, having become our justice, and sanctification, and redemption."
The schema of the Dogmatic Constitution on the Principal Mysteries of the Faith, drafted for the First Vatican Council (1869-1870), includes the unique mediation of Jesus Christ as one of these principal mysteries: "Truly, therefore, Christ Jesus is mediator between God and man, one man dying for all; he made satisfaction to the divine justice for us, and he erased the handwriting that was against us. Despoiling principalities and powers, he brought us from our longstanding slavery into the freedom of sons."
Except when it doesn't.