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'Bilayer' graphene shows tunable bandgap
Chemistry World ^ | 10 June 2009 | Jon Cartwright

Posted on 06/11/2009 12:11:53 AM PDT by neverdem

Since its discovery in 2004, the carbon-based material known as graphene has revealed a stream of attractive properties. Now, researchers in the US have shown that a two-layer version can deliver yet another: a wide, tunable bandgap. The discovery paves the way for new electronic devices, from lasers that change colour to electronic circuits that rearrange themselves. 

Graphene is a sheet of carbon just one atom thick, with a structure that resembles chicken wire. Single sheets of the material have proved to have record-breaking strength, high conductivity and high transparency. But recently some scientists have come to suspect that the most interesting properties might arise in two parallel sheets, or so-called bilayer graphene. 

Feng Wang and others at the University of California at Berkeley and Lawrence Berkeley National Laboratory have investigated the properties of bilayer graphene when it is performing within a field-effect transistor. Such transistors work using an electric field to control a semiconductor's conductivity, which in turn controls charge flow. In Wang and colleagues' device, however, there is a segment of bilayer graphene sandwiched between the transistor's 'source' and 'drain' electrodes, and the electric field serves to pull apart the graphene's highest valence band and the lowest conduction band. 

To witness this effect, the researchers used infrared microscopy and monitored the absorption spectrum. Peaks in the spectrum revealed the crucial bandgap, which the electric field could tune from zero to over 250 meV.  

Graphene bilayer device

Optical microscopy image of the bilayer device (top view). The bilayer graphene is the dark patch between source and drain.

© Nature

Wang told Chemistry World that the tunable bandgap, which generally determines a material's transport and optical properties, will enable 'flexibility and optimisation' of electronics and photonics. He says it could be used to control the colour emitted from lasers and other light sources. Moreover, because it can make insulators turn into semiconductors, and vice versa, he believes it might lead to electronic circuits that can be programmed in the field. 

Yu-Ming Lin, a graphene scientist at IBM's T. J. Watson Research Center in New York, said the wide bandgap in bilayer graphene will allow the creation of high-speed digital switches. 'I think this paper is very interesting and the results are definitely important to the field,' he added. 

However, Antonio Castro-Neto, a researcher at Boston University who has also studied tunable bandgaps in bilayer graphene, thinks there is still much more to be learned. He notes that bilayer graphene's density of states -- that is, the number of energy states available for occupation -- is finite, which indicates there should be complex, many-body effects. 'These systems may be able to show magnetic or superconducting properties that have not been explored yet,' he said. 

 

 

 

 

References

Y Zhang et al, Nature, 2009. DOI: 10.1038/nature08105

Also of interest

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graphane

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Graphene can be reversibly converted into its electrically insulating alter ego, graphane


Graphene powder

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TOPICS: Culture/Society; News/Current Events; Technical
KEYWORDS: bilayergraphene; chemistry; physics; tunablebandgap

1 posted on 06/11/2009 12:11:53 AM PDT by neverdem
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To: neverdem

Cool.


2 posted on 06/11/2009 12:19:09 AM PDT by Redcloak ("Oh, bother!" said Pooh, as he chambered his last round.)
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To: neverdem

Sounds like we will soon have a GFET.


3 posted on 06/11/2009 12:28:51 AM PDT by SpaceBar
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To: neverdem

First headline in over 10 years here on FR that I had no clue what in the world it meant.


4 posted on 06/11/2009 12:40:08 AM PDT by exit82 (The Obama Cabinet: There was more brainpower on Gilligan's Island.)
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To: SpaceBar

Graphine Field Effect Transistor?

I am wondering about the fabrication processes that will need development.


5 posted on 06/11/2009 1:06:02 AM PDT by Lexinom
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To: neverdem

Thailand?


6 posted on 06/11/2009 1:09:02 AM PDT by SIDENET ("Join me or die. Can you do any less?" -Mr. Sparkle)
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To: exit82

It sounds really cool, though, doesn’t it?


7 posted on 06/11/2009 1:27:34 AM PDT by skr (May God confound the enemy)
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To: exit82

Funny thing is that because of FreeRepublic, I actually knew what the headline meant!

Cool news pops up in the middle of the night...


8 posted on 06/11/2009 2:31:08 AM PDT by Skenderbej
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To: neverdem

Could be as big as the (invention of) the laser.

At any rate, will be remembered long after the current president is gone and his name no longer mentioned by the MSM.


9 posted on 06/11/2009 3:17:15 AM PDT by Steely Tom (RKBA: last line of defense against vote fraud)
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To: decimon; Robert A. Cook, PE; snarks_when_bored; Physicist; Myrddin; Wonder Warthog
Like, *PING*, dudes.

Cheers!

10 posted on 06/11/2009 3:30:47 AM PDT by grey_whiskers (The opinions are solely those of the author and are subject to change without notice.)
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To: neverdem

thanks


11 posted on 06/11/2009 3:33:20 AM PDT by cowtowney
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To: exit82
First headline in over 10 years here on FR that I had no clue what in the world it meant.

I had some trouble with this one from last night, especially the comment:

Ann Coulter on Hannity

When asked by Hannity the families are now involved,Ann shot back with"Have you seen his wife"

SMACKDOWN!

12 posted on 06/11/2009 4:20:09 AM PDT by Right Wing Assault ( Obama, you're off the island!)
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To: neverdem
I do hope Feng Wang and Yu-Ming Lin will continue their work here in the US, though I won't be too surprised if their next reported breakthroughs are reported from some other part of the world.
13 posted on 06/11/2009 5:29:07 AM PDT by GBA
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To: Steely Tom; grey_whiskers; neverdem; patton; CholeraJoe; Cyber Liberty

“Graphene can be reversibly converted into its electrically insulating alter ego, graphane”

I think this will be the biggie ...


14 posted on 06/11/2009 5:58:16 AM PDT by Robert A Cook PE (I can only donate monthly, but socialists' ABBCNNBCBS continue to lie every day!)
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To: Robert A. Cook, PE
The graphene-graphane-graphene conversion is a hydrogenation (chemical) process; not necessarily amenable to high speed control. OTOH, I can see applications as a chem (hydrogen) sensor/control in hydrogen-fueled applications.

OTOH, the double-layer. electrically tunable bandgap brings on visions of ultra-thin, flexible color displays, etc.

~~~~~~~~~~~~~

It is stuff like this that almost makes me want to give up retirement and get back in my micro-materials science lab... ;-)

15 posted on 06/11/2009 7:49:35 AM PDT by TXnMA ("Allah": Satan's current alias...!!)
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To: El Gato; Ernest_at_the_Beach; Robert A. Cook, PE; lepton; LadyDoc; jb6; tiamat; PGalt; Dianna; ...
Vitamin C helps stop diabetes damage

Stem Cells for Dummies

FReepmail me if you want on or off my health and science ping list.

16 posted on 06/11/2009 7:56:14 AM PDT by neverdem (Xin loi minh oi)
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To: Ernest_at_the_Beach; ShadowAce; blam

Thanks neverdem.


17 posted on 06/11/2009 6:05:28 PM PDT by SunkenCiv (https://secure.freerepublic.com/donate/__Since Jan 3, 2004__Profile updated Monday, January 12, 2009)
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