Posted on 04/21/2008 10:04:15 PM PDT by blam
Terracotta army has egg on its face
Monday, 21 April 2008 Jennifer Viegas
v Discovery News
Soldiers of China's terracotta army were once brightly painted, then preserved with an egg coating (Source: Reuters/Philippe Wojazer)
China's terracotta army, a collection of 7000 soldier and horse figures in the mausoleum of the country's first emperor, was covered with beaten egg when it was made, scientists say.
According to German and Italian chemists who have analysed samples from several figurines, the egg was as a binder for colourful paints, which went over a layer of lacquer.
"Egg paint is normally very stable, and not soluble in water ... This makes it less sensitive to humidity and moisture," says German co-author Catharina Blaensdorf, a scientist at the Technical University of Munich.
Egg proteins would have also ensured the adhesion of the paint to the lacquer, while also giving the paint thickness and texture, says Blaensdorf's Italian colleague Ilaria Bonaduce, of the University of Pisa.
For the study, which is published in the latest issue of the Journal of Cultural Heritage, the researchers took samples from warrior figurine faces, kneeling archers, swans and paint fragments found on the ground inside the 210 BC mausoleum.
They separated the flakes chemically to isolate the ingredients and then inserted them into a machine to determine their composition.
The researchers thought animal glue might have served as a binder, but all of the data pointed to egg instead.
The pigments, they found, were bone white, lead white, cerussite (which sparkles), quartz, cinnabar, malachite, charcoal black, copper salts, Chinese purple and azurite.
Bright hues were important "because colour was precious and a colourful army was the best, and an emperor could demand the best", says Blaensdorf.
Built to last The sturdy terracotta and thick, eggy paint add to the conclusion that the army was also built to last.
The mausoleum was even booby-trapped, with rigged crossbows to stop would-be thieves.
Eighty master potters left their signatures on the terracotta figures. These names show some individuals came from the imperial court, while other artists appear to have been respected local craftsmen.
Some official names overlap with those found on sewage pipes and floor tiles found in other locations.
"So it seems there was an office for making pottery [within] the imperial court," says Blaensdorf.
Historical significance
Erika Ribechini, a scientist in the Department of Chemistry and Industrial Chemistry at the University of Pisa, who did not work on the project, says the new findings "are very well presented".
"Even though the terracotta army is very famous," she says, not much is known about it.
"[The egg discovery] is particularly fascinating in terms of its historical significance, because roughly in the same period, in the Roman Empire and in ancient Greece, the artists used to utilise egg as a binder in creating mural and stone paintings."
The research is likely to help art restorers to repair and preserve the terracotta army.
Oh how funny! Thanks so much!
Hmmmm, yes.
No idea.
7,000 terracotta warriors. And hundreds of horses and chariots and such. It’s really quite staggering to consider.
They must have really liked that guy.
FEAR!
They say he went crazy before he died, probably of mercury poisioning. He would take anything that anyone said would extend his life.
I don’t believe so, I am not sure if the mollusk you describe is only native to the Mediterranean or if it is also found in waters near China. The Chinese purple was a manufactured synthetic quite similar to the way modern paint pigments are made.
http://en.wikipedia.org/wiki/Han_Purple
BaCuSi2O6
Purple was expensive in Europe because it was so scarce. The Chinese purple seems to have been produced quite readily, or at least enough to paint several thousand life size statues.
Since it was a pigment and not a dye, I would have been surprised to learn it had a murex precursor.
FR is a neat place: there are lots of folks here who can teach this physical chemist a thing or two... Knuckle-dragging conservatives, indeed! '-)
Now that he fulfilled his lifelong dream, whats he going to do for the rest of his life? Go to pot? Is that going to be his Clay-im to fame?
“Now that he fulfilled his lifelong dream, whats he going to do for the rest of his life? Go to pot? Is that going to be his Clay-im to fame?”
LOL!
If it has anything to do with clay, perhaps we’ll read about it in breaking news.
I couldn’t resist the opportunuty for a pun. I wish him the best and I think that was a clever prank.
“I couldnt resist the opportunity for a pun.”
Me too!
The “breaking” news was in response to your “clay” and “pot,”.....breaking?
Now how could have I been more clever? ( I need suggestions...really!)
Like you, I love puns! They are so much fun!
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