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Serendipity yields a process to convert carbon dioxide directly into ethanol
Watts Up With That? ^ | October 18, 2016 | By Anthony Watts

Posted on 10/19/2016 7:39:21 AM PDT by Brad from Tennessee

OAK RIDGE, Tenn.,—In a new twist to waste-to-fuel technology, scientists at the Department of Energy’s Oak Ridge National Laboratory have developed an electrochemical process that uses tiny spikes of carbon and copper to turn carbon dioxide, a greenhouse gas, into ethanol. Their finding, which involves nanofabrication and catalysis science, was serendipitous. Video follows.

“We discovered somewhat by accident that this material worked,” said ORNL’s Adam Rondinone, lead author of the team’s study published in ChemistrySelect. “We were trying to study the first step of a proposed reaction when we realized that the catalyst was doing the entire reaction on its own.”

The team used a catalyst made of carbon, copper and nitrogen and applied voltage to trigger a complicated chemical reaction that essentially reverses the combustion process. With the help of the nanotechnology-based catalyst which contains multiple reaction sites, the solution of carbon dioxide dissolved in water turned into ethanol with a yield of 63 percent. Typically, this type of electrochemical reaction results in a mix of several different products in small amounts. . .

(Excerpt) Read more at wattsupwiththat.com ...


TOPICS: Extended News
KEYWORDS: co2; ethanol
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1 posted on 10/19/2016 7:39:21 AM PDT by Brad from Tennessee
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To: Brad from Tennessee

My personal thought is that if they can’t make that process cheaper than cracking oil into gas without some effing government subsidy like for ethanol, then they should STFU.


2 posted on 10/19/2016 7:42:55 AM PDT by Gaffer
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To: Brad from Tennessee

Just fill your tank with water and drop a pill in.

Voila!!!


3 posted on 10/19/2016 7:43:38 AM PDT by Iron Munro (If Illegals voted Rebublican 50 Million Democrats Would Be Screaming "Build The Wall!")
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To: Brad from Tennessee
Clean coal fired plants, that release no CO2, and run on abundant, cheap, coal!

A greenies dream come true! Right? WRONG!

'Environmentalists', don't care if energy is ,renewable, or clean, they wnat energy that is EXPENSIVE. That is their only concern.


4 posted on 10/19/2016 7:44:58 AM PDT by MMaschin (The difference between strategy and tactics!)
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To: Brad from Tennessee

Still technology meets the 21st century....the moonshiners are gonna have some competition.

Actually I could easily see how some alcohol beverage companies may want to leverage this to reduce process costs and better control alcohol content. Then it would just be a matter of how to appropriately ‘flavor’ it.


5 posted on 10/19/2016 7:45:00 AM PDT by reed13k (r)
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To: Brad from Tennessee
...carbon, copper and nitrogen and applied voltage...

In other words, the process requires energy.
Not surprising, it's the law of physics.
Where will that energy come from? Will it be cost effective?

6 posted on 10/19/2016 7:45:33 AM PDT by BitWielder1 (I'd rather have Unequal Wealth than Equal Poverty.)
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To: Gaffer

My personal thought is that they can take that ethanol and shove it up their rectum.

I am in the middle of tearing down every one of my small engines (weed wackers, leaf blowers, chain saws) to replace the fuel lines DUE TO ETHANOL.


7 posted on 10/19/2016 7:46:03 AM PDT by UCANSEE2 (Lost my tagline on Flight MH370. Sorry for the inconvenience.)
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To: UCANSEE2

Made me laugh.

I’ve been there.

http://www.pure-gas.org/index.jsp?stateprov=KS


8 posted on 10/19/2016 7:48:59 AM PDT by lacrew
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To: BitWielder1

Some of the informed commentators at WUWT.com have read the article and done the calculations to show that this is far from a viable anything. The nanocatalyst stuff is intriguing but in a far more basic way.


9 posted on 10/19/2016 7:50:54 AM PDT by bjc (Show me the data!)
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To: Brad from Tennessee

This joins a number of similar technologies going back six or seven years that I know of. Success would be making money at it.

All of these discoveries point out the low relative cost of oil, and that there should be no restraints on oil production because there are plenty of viable alternatives should oil TRULY become too expensive.


10 posted on 10/19/2016 7:52:11 AM PDT by jjotto ("Ya could look it up!")
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To: Gaffer
My personal thought is that if they can’t make that process cheaper than cracking oil into gas without some effing government subsidy like for ethanol, then they should STFU.

A lot of detail is left out:

  1. What's the cost of manufacturing the catalyst? (it's nanotechnology)
  2. Does the catalyst degrade over time? What's the estimated lifetime?
  3. What's the required power in kilowatt hours, per unit of ethanol, including any distillation to remove the water?

I would think that it violates some law of physics to convert carbon dioxide and water back into a hydrocarbon, and use less energy than was yielded by the original combustion.

Otherwise, it wouldn't be difficult to build a perpetual motion machine.

11 posted on 10/19/2016 7:53:52 AM PDT by justlurking
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To: BitWielder1

My guess is that the process is fairly slow, and doesn’t produce great volumes of ethanol. If the voltage requirement isn’t too high, it might be viable to do this using a two-layer solar panel: the top layer is the photo cells producing the voltage, feeding a layer just underneath of the carbon-copper catalyst (maximize surface area) that runs more or less continually producing a small but steady stream of ethanol. Get a field of these going and you might have something.


12 posted on 10/19/2016 7:54:15 AM PDT by Little Pig
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To: Brad from Tennessee
Conservation of Energy.

It's not just a good idea... IT'S THE LAW!

To change a low-energy-state substance, like Carbon Dioxide, into a fuel, like Ethanol, energy must be expended. This process can be made more efficient through the use of catalysts, but you can't get something for nothing.

The energy will have to come from somewhere. It will probably come from the electric grid, which means it will come from coal or other fossil fuels.

So, if you draw the big box around the whole life cycle, you use electricity, which produces Carbon Dioxide, to change Carbon Dioxide to Ethanol. This Ethanol can then be burned to produce energy, which will release all of the Carbon Dioxide back into the environment.

So, the only question is, is the amount of energy released by the burning of the Ethanol greater or less than the amount of energy used to change the Carbon Dioxide into Ethanol. Unfortunately, it is an absolute physical reality that the amount of energy released must be less than the amount of energy consumed. There is no such thing as a free lunch.

So, in order to minimize the amount of Carbon Dioxide in the environment, if you're into that sort of thing, is to do nothing. This process cannot do anything but make the amount of Carbon Dioxide in the environment go up.

13 posted on 10/19/2016 7:55:28 AM PDT by Haiku Guy
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To: UCANSEE2
My personal thought is that they can take that ethanol and shove it up their rectum.

Haha! Kindred spirits... :0)

I cannot even begin to describe all the low life descriptions of its proponents are and the complete downside of ALL of it.

Nothing good or worthwhile comes from ethanol when there are other sources of fuel available.

14 posted on 10/19/2016 7:56:48 AM PDT by Gaffer
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To: Brad from Tennessee

This could solve energy needs in perpetuity. Or at least alcohol needs.


15 posted on 10/19/2016 7:58:57 AM PDT by Gunpowder green
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To: UCANSEE2

They need to find a way to use ethanol other than burning it. Ethanol is much dirtier than gasoline per BTU, hence per mile driven.


16 posted on 10/19/2016 7:59:39 AM PDT by D Rider
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To: UCANSEE2

They need to find a way to use ethanol other than burning it. Ethanol is much dirtier than gasoline per BTU, hence per mile driven.


17 posted on 10/19/2016 7:59:41 AM PDT by D Rider
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To: Brad from Tennessee

Hey DOE, I have a process for turning ethanol’s base material into methane. Any interest?


18 posted on 10/19/2016 8:00:19 AM PDT by PeteePie (Righteousness exalts a nation, but sin is a reproach to any people - Proverbs 14:34)
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To: BitWielder1
The article mentioned solar so that it can be used when the solar panels produce more than can be used. It's a very interesting idea, especially being able to create ethanol electrically rather than biologically with yeast. I wish it gave some idea of the ratio of energy in vs. energy from burning the alcohol out.

Now can I get a hat with a solar panel and this catalyst so that I can turn my own breath into alcohol and dump my old beer can hat?

19 posted on 10/19/2016 8:00:22 AM PDT by KarlInOhio (If Muammar Gaddafi had donated to the Clinton Foundation he would still be alive and in power today.)
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To: justlurking

The whole crux of the matter is that Oak Ridge is a government laboratory that is operated by a private company.

They, like all the other leech companies sucking off the government have to come up with new and exciting promising theories, processes and gambits to hoodwink politicians something worthwhile can be done. All horseshit that will prove to be just a big a boon as the efficacy of ethanol

And any user of ethanol in their car, lawn mower, yard tools, etc. knows what a crock of sh!t it is.


20 posted on 10/19/2016 8:00:34 AM PDT by Gaffer
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