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From fibre to fuel in a flash - Chemists convert cellulose to potential biofuel without enzymes.
Nature News ^ | 11 September 2008 | Philip Ball

Posted on 09/11/2008 7:11:20 PM PDT by neverdem

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No abstract is available. I wonder why acid hydrolysis wasn't tried before?
1 posted on 09/11/2008 7:11:21 PM PDT by neverdem
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To: neverdem

Now if they could only make fuel out of Desert Broom!


2 posted on 09/11/2008 7:14:13 PM PDT by SubMareener (Become a monthly donor! Free FreeRepublic.com from Quarterly FReepathons!)
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To: neverdem

Because of this I guess.

“These conditions are pretty nasty,” says Dumesic. Handling highly corrosive concentrated hydrochloric acid in an industrial process is no easy matter. But Mascal counters that “engineering know-how and materials science have advanced to the point where this is not a critical issue”. Dumesic adds that it could be challenging to remove all traces of chlorine from the final product, which is crucial if it is to be used as a fuel.


3 posted on 09/11/2008 7:15:29 PM PDT by saganite (Obama is a political STD)
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To: neverdem
Now if they can figure out how I can transfer some cellulite to the gas tank.
4 posted on 09/11/2008 7:17:49 PM PDT by itsthejourney (Sarah-cuda IS the right reason)
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To: neverdem

Nitrocellulose is made into gun powder, should work.


5 posted on 09/11/2008 7:19:23 PM PDT by lookout88 (Combat search and rescue officer's dad.)
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To: itsthejourney
Now if they can figure out how I can transfer some cellulite to the gas tank.

Rosie O'Donnell and Michael Moore could fuel half the nation.
6 posted on 09/11/2008 7:23:55 PM PDT by Army Air Corps (Four fried chickens and a coke)
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To: neverdem

Thirty years ago I saw a report of an experiment where hydrolysis of cellulose was accomplished very rapidly with concentrated warm sulfuric acid. The lab was somewhere in the British isles.


7 posted on 09/11/2008 7:24:49 PM PDT by dr huer
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To: neverdem

bmflr


8 posted on 09/11/2008 7:31:00 PM PDT by Kevmo (Obama Birth Certificate is a Forgery. http://www.freerepublic.com/tag/certifigate/index?tab=articles)
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To: neverdem

Very interesting and encouraging. I think cellulosic feedstocks make a lot of sense, but according to process folks I’ve talked with, they’re incompatible with today’s biorefineries, especially on the front-end. Granted the plants could be modified and new ones built, but it’s an issue. But on the other hand, todays ethanol plants are located in corn producing areas, and cellulosic plants should be located near where the switchgrass or whatever is grown.


9 posted on 09/11/2008 7:43:48 PM PDT by bigbob
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To: neverdem

I was four when I first heard the announcement of the perfect ‘acid’; nothing could withstand its solvent properties; alas, it remains a commercial failure as no one has found a way to package it and put it to use.


10 posted on 09/11/2008 7:49:30 PM PDT by Old Professer (The critic writes with rapier pen, dips it twice, and writes again.)
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To: neverdem
"There are still plenty of hurdles to make the new process work. "These conditions are pretty nasty," says Dumesic. Handling highly corrosive concentrated hydrochloric acid in an industrial process is no easy matter."

Cheez---somebody needs to tell these guys that this isn't the eighteenth century. The chemical industry handles "concentrated hydrochloric acid" in multi-ton quantities on a daily basis. Yeah, it's corrosive, and yes, "we have the technology".

11 posted on 09/11/2008 7:54:15 PM PDT by Wonder Warthog ( The Hog of Steel)
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To: neverdem

let me guess 10 yrs out with good grant money


12 posted on 09/11/2008 7:56:53 PM PDT by Flavius (war gives peace its security)
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To: saganite; neverdem
"I wonder why acid hydrolysis wasn't tried before? "

It has been. What these guys are doing differently is continuously extracting the product as it is formed, thus shifting the reaction equilibrium.

"“These conditions are pretty nasty,” says Dumesic. Handling highly corrosive concentrated hydrochloric acid in an industrial process is no easy matter. But Mascal counters that “engineering know-how and materials science have advanced to the point where this is not a critical issue”. Dumesic adds that it could be challenging to remove all traces of chlorine from the final product, which is crucial if it is to be used as a fuel."

No, none of this is particularly problematic. The chemical industry knows how to do this stuff. They do more complicated and difficult things on a daily basis.

13 posted on 09/11/2008 7:58:39 PM PDT by Wonder Warthog ( The Hog of Steel)
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To: neverdem

It seems to me that a sustainable fuel source is aborted Democrat fetuses. There is always a supply and they could be mashed up and fermented which should yield burnable fuel. What could be better than a Prius running on the owner’s aborted fetus? Now there is a true environmentalist!!!


14 posted on 09/11/2008 8:29:16 PM PDT by Rembrandt (We would have won Viet Nam w/o Dim interference.)
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To: El Gato; Ernest_at_the_Beach; Robert A. Cook, PE; lepton; LadyDoc; jb6; tiamat; PGalt; Dianna; ...
Gamma-Ray Burst Aimed Directly at Earth

Detailed Study on Spread of H.I.V. in U.S.

The Large Hadron Collider

FReepmail me if you want on or off my health and science ping list.

15 posted on 09/11/2008 8:36:30 PM PDT by neverdem (I'm praying for a Divine Intervention.)
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To: neverdem
a strong acid to break down the cellulose.

Nitric acid...

Nitro cellulose = gun grass?

Chop it up fine, blow it into the cylinders, and diesel it?

If it works for grass, maybe it will also work for ‘grass’, giving the Hippies a use for their seeds?

16 posted on 09/11/2008 9:04:56 PM PDT by ApplegateRanch (The Great Obamanation of Desolation, attempting to sit in the Oval Office, where he ought not..)
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To: bigbob

I think that oil from ALGAE is going to be the best way to capture solar energy for transportation. Algae were the primary source of the fossil petroleum that we use today.

One pathway extracts raw algal oil from the dried algae, and processes it into biodiesel that is very similar to other plant oils.

The other pathway uses algae that produce a “green crude” - it is literally green in color - that can be fed directly into the petroleum refineries in use today.

In either case, the productivity of algae per acre is far higher than any land-based crop, and the requirement for fresh water is almost eliminated - most strains of algae grow in sea water, brackish water, or even sewage.


17 posted on 09/11/2008 9:18:07 PM PDT by MainFrame65 (The US Senate: World's greatest PREVARICATIVE body!.)
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To: MainFrame65
I believe that you are correct as to the potential for algae as a fuel source, and especially so for warm climates and underdeveloped countries. The technology is undeveloped though, and I do not know of a single operational algae to fuel facility, even in prototype form.
18 posted on 09/11/2008 9:45:36 PM PDT by Rockingham
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To: neverdem

Innerestin’


19 posted on 09/11/2008 10:20:21 PM PDT by El Sordo
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To: AdmSmith; Berosus; Convert from ECUSA; dervish; Ernest_at_the_Beach; Fred Nerks; george76; ...

thanks neverdem.

The Bum Rap on Biofuels
American Thinker | 5-13-08 | Herbert Meyer
Posted on 05/14/2008 3:59:06 AM PDT by Renfield
http://www.freerepublic.com/focus/f-news/2015711/posts

Campaign to vilify ethanol revealed
ethanol producer Magazine | May 16, 2008 | By Kris Bevill
Posted on 05/17/2008 9:22:13 AM PDT by Kevin J waldroup
http://www.freerepublic.com/focus/f-news/2017389/posts


20 posted on 09/11/2008 10:20:55 PM PDT by SunkenCiv (https://secure.freerepublic.com/donate/_______Profile hasn't been updated since Friday, May 30, 2008)
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