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To: Arkie2

If we could just use nano technology somehow to reduce dependence on oil - that could solve a lot of problems!


41 posted on 08/19/2005 9:37:57 AM PDT by marvlus
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To: marvlus

The article I posted for this thread alluded to improvements in batteries. The article below expands on that and I believe the following article was written before this manufacturing breakthrough. Why does that matter to reducing dependence on oil? Better batteries for electric cars, better batteries for storage at wind farms and solar arrays. Batteries are important in the last two applications because they could serve to even out the production of electricity.




Introduction Ultracapacitors or double layer capacitors (DLCs) are energy storage devices whose operation is based on the double layer effect. By utilizing highly porous carbon material with a surface area up to 2000m2/g as electrodes (as in Fig. 3) commercial DLCs can achieve a energy density (6Wh/kg) much greater than the energy density of a conventional capacitor. However, this figure is much lower than the energy density reached by Lithium-Ion batteries (120Wh/kg).

Our analysis shows that the utilization of a matrix of vertically aligned CNTs as electrode structure, can lead to an ultracapacitor characterized by a power density greater than 100kW/kg (three orders of magnitude higher than batteries), a lifetime longer than 300,000 cycles, and an energy density higher than 60Wh/kg.


Double Layer Principle:

The significant energy density improvement of DLCs over other types of capacitors arises from the higher specific capacitance achieved with DLCs that can be up to 180 F/g. This result can be explained by the double layer principle discovered by Helmholtz in 1853. According to the Helmholtz model, when two electrodes, between which a potential is established, are immersed in an ionic solution, ions from the electrolyte migrate to the interface between the oppositely charged electrode and the solution.


Nanotube Enhanced Ultracapacitor:

A matrix of vertically aligned carbon nanotube (CNT) has been investigated as a DLC electrode. Our analysis shows that this configuration can provide a combination of high power density (more than four orders of magnitude greater than fuel cells) and energy density (comparable to Li-Ion batteries). The significant enhancement in the achievable DLC power density derives from the high conductivity obtainable with CNTs, which in the limit of a few microns in length present ballistic conduction. The energy density improvement of a “nanotube enhanced electrode” is due to the higher effective surface area obtainable with a structure based on vertically aligned nanotubes over activated carbon.

Recently, we have been able to grow straight single wall nanotubes (SWNT) with diameters varying from 0.7 to 2nm and a length of several tens of microns. We grew SWNTs via thermal chemical vapor deposition (CVD) on a silicon substrate coated with a catalyst consisting of nanocolloids of aluminum oxide (AlO2) coated with iron nitrogen oxide (Fe(NO3)3). The average diameter of the catalyst seeds was 3nm. The substrate coated with catalyst was processed at 900°C at atmospheric pressure by CVD in an environment saturated with hydrogen (H2) and argon (Ar). As stockfeed gas we used methane (CH4). Single wall nanotubes grew from the Fe(NO3)3 seeds via decomposition of methane at the catalyst interface.

http://lees.mit.edu/lees/projects/cnt_ultracap_project.htm



43 posted on 08/19/2005 10:16:13 AM PDT by Arkie2 (No, I never voted for Bill Clinton. I don't plan on voting Republican again!)
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To: marvlus
If we could just use nano technology somehow to reduce dependence on oil - that could solve a lot of problems!

Lightweight vehicle parts, more efficient performance engines, appliances that use less poower. All that will contribute to our eventual independence from raghead oil.

81 posted on 08/20/2005 12:18:50 AM PDT by FierceDraka (The Democratic Party - Aiding and Abetting The Enemies of America Since 1968)
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