The prefix “un-” means, so far as I know, not.
So, a new word with that prefix means the opposite of the original.
Unconditional surrender is the opposite of conditional surrender. Don't think of those two words as synonyms.
As to Orwell and his book, he was concerned about sinister forces abusing language for manipulative purposes.
So, do you mean by that, that some or all of the uses I cited above were "sinister forces abusing language for manipulative purposes"?