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Hybrid copper-gold nanoparticles convert CO2 (To Hydrocarbons!)
http://phys.org ^ | 04-11-12 | Jennifer Chu - Provided by Massachusetts Institute of Technology

Posted on 04/11/2012 8:26:05 AM PDT by Red Badger

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To: E. Pluribus Unum

Copper — the stuff of pennies...

Actually, that would be Zinc.

Just goes to show you that researchers and writers know little about money.


41 posted on 04/11/2012 9:58:23 AM PDT by mountainlion (I am voting for Sarah after getting screwed again by the DC Thugs.)
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To: thackney

Silly comment.

Of course you wouldn’t use methane to produce hydrogen to be used to produce methane. One of the holy grails of catalytic chemistry has been efficient water splitting. That is the best place to find hydrogen for this process. And yes, it requires energy. My point was, simply, that if solar energy could create the current necessary to power this reaction, it would be an efficient way to produce a mobile fuel.

Of course, by trapping more solar energy, we could change the earth’s heat balance and create global warming.

(BTW, I am not a warmist, but I believe it is prudent to explore as many alternate energy processes as we can. It’s just good science.)

“Creativity is putting known facts together in new and unusual ways.”


42 posted on 04/11/2012 9:59:18 AM PDT by mike70
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To: Skepolitic

You’re still ahead of me - everything I know about hydrocarbons I learned from watching McGyver. :-)


43 posted on 04/11/2012 10:00:33 AM PDT by knittnmom (Save the earth! It's the only planet with chocolate!)
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To: BJ1

As for the Hydrogen, you would likely get it from water, but you need energy to separate it. You could get it from H2S, which is interesting because its a byproduct of hydrocarbon refining.

Either way, you have to add energy here to get the hydrogen. Question is whether you could generate enough using solar to make it work at scale.

The earth is producing all kinds of DC power everyday, just by having its metal core turning within the magnetosphere - 186,000 lightening strikes a day.

I saw a video of a refueling tanker manifesting ‘St. Elmo’s Fire’ and the fuel nozzle arc’ing and sparking against the jet its trying to refuel.

Consider they are likely using JP-4, which is pretty flammable and not JP-5, which you could use to put out a cigarette.

Lot’s of free electrical energy out there. It’s just a matter of putting lightning in a bottle, as it were.


44 posted on 04/11/2012 10:08:05 AM PDT by RinaseaofDs (Does beheading qualify as 'breaking my back', in the Jeffersonian sense of the expression?)
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To: mike70

But electrolysis of water is far more expensive than steam reforming methane. That makes a bad idea even worse.

This scam is not about energy production, it is about carbon nature. They may have improved the losses but it still operates at a loss.


45 posted on 04/11/2012 10:10:59 AM PDT by thackney (life is fragile, handle with prayer)
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To: Squawk 8888

Apart from recovering and recycling waste CO2, another angle to this process (if it is efficient enough) is that it could be another effective way to store and transport electric power. As methane, it transports nicely.


46 posted on 04/11/2012 10:13:24 AM PDT by Ramius (Personally, I give us one chance in three. More tea anyone?)
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To: far sider

Isn’t thermodynamics the science that determines the size of showerheads and water reservoirs for toilets as developed by congresscritters?


47 posted on 04/11/2012 10:14:35 AM PDT by 353FMG
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To: Red Badger

Hmmm. I believe I’ve used copper to make ethanol too! :)


48 posted on 04/11/2012 10:18:01 AM PDT by IamConservative (Shall I try and perhaps fail or shall I do nothing without fail?)
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To: JimRed
How much voltage, for how long? IOW, will it cost more to supply the necessary voltage than the net value of the fuel produced?

Will it end up as inefficient as the other "green" technologies?

Well, let's see...First you burn coal to make steam to turn a turbine that drives a generator that produces electricity. The process also produces CO2 which can be reacted with a copper/gold electrode in an undefined solution to produce methane (natural gas). So lets just burn the methane along with the coal, oh oh, we just produced more CO2...Back to the magic cells to make more methane.

At some point could we drop the coal altogether and just burn methane to produce electricity and CO2 while reacting the CO2 with the copper/gold electrodes and the secret sauce (with just a pinch of the electricity produced, leaving enough power to keep our customers smiling!) Let's look a little closer, we have a closed process with a fixed amount of CO2 which we convert to methane using a catalyst and electricity. We then burn the methane, extracting heat to produce electricity and more CO2 to continue the process indefinitely.

Neat! Except that the laws of physics regarding the conservation of energy require that the amount of energy needed to synthesize the methane will be greater than what you can recover by burning the same amount of as fuel. This is why all thermodynamic processes reject heat to the environment (cooling towers!!).

Lastly, converting all the CO2 produced by a coal fired power plant to methane or methanol does not destroy the gas forever, it hides it as unburnt hydrocarbons in the newly produced fuels. As soon as those fuels are burnt, presto, the same amount of CO2 is released into the environment, the energy recovered will be less then the energy input to the synthesis as electricity. And what a long strange trip it's been...

The closed box that produces perpetual energy output is just as imposable as the proverbial "free lunch".

Regards,
GtG

49 posted on 04/11/2012 10:20:51 AM PDT by Gandalf_The_Gray (I live in my own little world, I like it 'cuz they know me here.)
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To: LucianOfSamasota

Sounds like enough energy to keep the stack blowing eh!


50 posted on 04/11/2012 10:42:45 AM PDT by muawiyah
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To: LucianOfSamasota
That's downstream from the initial coal fire ~ crank the numbers into the total process that's just gotta' take the average total burn including the coal burn under the EPA standards!

I have no doubt they will be utterly mystified!

51 posted on 04/11/2012 10:48:05 AM PDT by muawiyah
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To: IamConservative

...and I bet the Feds didn’t like it!........


52 posted on 04/11/2012 11:22:12 AM PDT by Red Badger (Think logically. Act normally.................)
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To: Ramius
You figured out the value. If you have water, waste CO2 and the catalyst, you can transform back to methane (storable) with electrical input. Photo voltaic cells can capture solar energy and provide the input to do the conversion. Methane is much easier to store than hydrogen. In a closed system such as a space craft, that would be a useful way to manage the carbon cycle. It doesn't make much sense on earth. We can burn plentiful methane and let green plants do the carbon/nitrogen fixation for us using sunlight. My lawn is a spectacular tool for capturing CO2 all summer.
53 posted on 04/11/2012 11:40:06 AM PDT by Myrddin
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To: Myrddin

Roger that. I was also thinking of long distance transportation. One of the difficulties of electrical generation is that it needs to be fairly close to the consumer. Long distance transmission is terribly inefficient, and means losing non-trivial amounts of power the farther it goes. This sounds like it might be a good way of storing up energy in one place and moving it over long distances.


54 posted on 04/11/2012 1:38:04 PM PDT by Ramius (Personally, I give us one chance in three. More tea anyone?)
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To: Ramius
This sounds like it might be a good way of storing up energy in one place and moving it over long distances.

CNG meet pipeline. Solar electric + water + CO2 ->CNG.

55 posted on 04/11/2012 1:52:30 PM PDT by Myrddin
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To: Ramius
The equation might work with "wind electric" too. The key being "storage" via compressed methane.
56 posted on 04/11/2012 1:54:00 PM PDT by Myrddin
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To: Ramius
One of the difficulties of electrical generation is that it needs to be fairly close to the consumer.

We run HV transmission lines for hundreds of miles for cost effective generation to consumer.

Long distance transmission is terribly inefficient

A few percentage points of loss is terribly inefficient?

57 posted on 04/11/2012 1:59:20 PM PDT by thackney (life is fragile, handle with prayer)
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To: thackney

I thought the loss on long distance high voltage lines was more on the order of 10 or 20%. Is that wrong?


58 posted on 04/11/2012 3:55:31 PM PDT by Ramius (Personally, I give us one chance in three. More tea anyone?)
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To: Ramius

The electrical loss of electricity leaving the power plant, through the step-up transformers, across the high voltage transmission line, through the local substation including step-down transformer, across local distribution lines, through the end transformer to the customer meter totals 6~7% typically. The transmission line alone is a fraction of that total.

High Voltage DC lines have even less losses, but the stations of HVAC-HVDC are very expensive and this set up is normally only used to move power either through long distances without intermediate drop off, or systems isolated by frequency.

High Voltage transmission lines are used because as the voltage increases, for the same amount of power flow, current decreases. Losses are impedance (resistance plus reactance) times the current squared. If you double the voltage, halving the current, the losses are quartered. This why we use voltage up to 765kV in the US for long distances.


59 posted on 04/11/2012 6:29:09 PM PDT by thackney (life is fragile, handle with prayer)
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To: skinkinthegrass; AdmSmith; AnonymousConservative; Berosus; bigheadfred; Bockscar; ColdOne; ...

Thanks skinkinthegrass.


60 posted on 04/12/2012 10:09:13 PM PDT by SunkenCiv (FReepathon 2Q time -- https://secure.freerepublic.com/donate/)
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