I don't think you're right on the effectiveness of perfect condom use. A Johns Hopkins publications puts it at 97%, with average use at 86%.
http://www.infoforhealth.org/pr/h9/h9chap4.shtml
Mrs VS
Thank you for the correction.
Of course, "perfect use" is probably a pretty unrealistic situation or expectation for most people.
Symptothermal NFP has a perfect use effectiveness above 98%, BTW.