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Gasification may be key to U.S. ethanol
AP ^ | 03/04/07 | DIRK LAMMERS

Posted on 03/04/2007 5:03:09 PM PST by nypokerface

SIOUX FALLS, S.D. - The government awarded $385 million in grants last week aimed at jumpstarting ethanol production from nontraditional sources like wood chips, switchgrass and citrus peels. What's surprising is that half of the six projects chosen will use a process first discovered almost a century ago to turn coal into a gas.

President Bush set a goal in his State of the Union address of producing 20 percent of the nation's fuel supply from renewable resources by 2017. Much of those supplies will come from the conversion of corn into enthanol, fueled by a boom in new ethanol plant construction that's already under way.

But Thursday's forecast from the Agriculture Department that half of this year's U.S. corn crop will be consumed by ethanol producers has raised red flags. Critics say surging demand for corn could push up prices of everything from corn-sweetened soft drinks to meats, since corn is a common feed ingredient for livestock.

That helps explain why the Energy Department is placing a big bet on a process called gasification. Long hailed as a more environmentally friendly way to turn coal into electricity, the process might also provide a faster and eventually cheaper way to produce ethanol from a variety of renewable sources collectively known as biomass, some scientists say.

For corn-based ethanol plants, the process of producing ethanol is as simple as brewing beer: sugars are extracted from the corn kernels and then enzymes are added to ferment it into alcohol. But biomass feedstocks don't easily give up their starches, so more expensive steps are needed to ferment cellulose in high-pressure chambers that have limited amounts of oxygen, according to Lanny Schmidt, a University of Minnesota chemical engineer.

Energy Secretary Samuel Bodman pegged the current cost of gasification as being about twice as much as the average $1.10 per gallon cost at corn-based ethanol plants.

A gasifier turns plant material into a synthesis gas consisting mostly of carbon monoxide and hydrogen. The "syngas" then could be turned into a variety of fuels including ethanol, hydrogen and environmentally friendly versions of diesel or gasoline, Schmidt said.

"These gasifiers are some high-tech stuff with high pressures and some more complexities," he said. "But they're probably more versatile at the end of the day to modify them as the demand and supplies change."

Gasification is a fairly simple process, based on chemistry developed in the 1920s, said Robert Brown, an Iowa State University chemical engineering professor and director of the school's Office of Biorenewables Programs.

The syngas produced during gasification mixes more readily with chemical catalysts, so it could be more easily turned into other fuels, chemicals and materials. Just add steam and you could produce hydrogen to power a fuel-cell vehicle, Brown said.

Of the six companies awarded U.S. Department of Energy grants, three will use versions of fermentation technology. But two others will use gasification and one will use a hybrid of both technologies:

• Alico Inc., a LaBelle, Fla.-based agribusiness company, would get up to $33 million to turn yard waste, wood waste and citrus peel into syngas, which would then be converted into ethanol, electricity and hydrogen.

• Range Fuels Inc., of Broomfield, Colo., would get up to $76 million for a plant near Soperton, Ga., to convert timber scraps into syngas to make ethanol and methanol.

• Abengoa Bioenergy, a St. Louis-based division of Spain's Abengoa SA, would receive up to $76 million for an 11.4 million gallons-per-year plant in Colwich, Kan., that would use both biochemical and thermochemical processes to convert corn stalks, wheat straw and switchgrass.

The Energy Department helped demonstrate the viability of gasification in the mid-1990s when it awarded Georgia-based FERCO $9.2 million to help build a power plant running on wood chips. By 2001, the $18 million plant in Burlington, Vt., was generating more than 200 megawatt-hours of electricity a day.

To compete in the marketplace, companies will have to make sure their feedstock supplies are consistent, do more research into catalysts that turn syngas into fuels, and develop better materials to contain the thermochemical reactions, according to the Energy Department.

The syngas would have to be cleaned and conditioned to remove contaminants, which is an expensive task. Energy officials say companies will have to bring down those costs if they're to compete in the market.

Mark Paster, a U.S. Department of Energy technology development manager who's studying ways to turn biomass into hydrogen, said both fermentation and gasification "are very viable and both routes continue to be researched and developed."

Paster said biomass helps reduce greenhouse gasses, so any method that can reach commercial viability will be better than one based on fossil fuel.

"There may not be a single winner, just like there's no winner in how we produce electricity," he said. "We do it in a variety of ways."


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To: RegulatorCountry

"Coal Gas"


21 posted on 03/04/2007 5:46:22 PM PST by xcamel (Press to Test, Release to Detonate)
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To: nypokerface

We've had a DOE gassification pilot operation in Kingsport for a long time.

The Eastman technology is already a mature technology and has been for 25 years.


22 posted on 03/04/2007 5:51:44 PM PST by bert (K.E. N.P.)
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To: bert

They still require more energy than the end product produces.


23 posted on 03/04/2007 5:53:19 PM PST by xcamel (Press to Test, Release to Detonate)
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To: RegulatorCountry
The production of syngas, the subject of the article, isn't Fischer-Tropsch. The high pressure polymerization of syngas into higher weight hydrocarbons in the presence of an iron or cobalt catalyst is.
24 posted on 03/04/2007 5:54:34 PM PST by SpaceBar
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To: xcamel

That obversation is moot. They transform the coal gas into a myraid of products on which modern life is pretty much dependant.

In most cases they are the low cost producer


25 posted on 03/04/2007 5:59:19 PM PST by bert (K.E. N.P.)
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To: xcamel
ethanol is nearly as big a hoax as global warming

I agree. And the subsidies are nothing but pure pork.

26 posted on 03/04/2007 6:06:36 PM PST by D-Chivas
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To: flashbunny

Not a booddoogle.

A perfectly viable business as long as oil prices are high enough. What is high enough, now there is the question.

One good thing I will say about this program, at least they are not making fuel from food. Another good thing is that the money goes to farmers, ranch workers, wood producers and plant workers and not to some thug third-world dictator.

Hitler nearly took over Europe burning synthetic diesel in his tanks. South Africa lived for years on synthetic petroleum.

If nothing else, the Arabs fear that something like this will take their power away.


27 posted on 03/04/2007 7:53:28 PM PST by dangerdoc (dangerdoc (not actually dangerous any more))
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To: xcamel
ethanol is nearly as big a hoax as global warming

Like that pill you drop into the gas tank full of water and then drive off in the car with the carburetor that gets 100 miles to the gallon, riding on four tires that never wear out.

28 posted on 03/04/2007 8:01:00 PM PST by ChildOfThe60s (If you can remember the 60s......you weren't really there)
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To: xcamel

Welcome to entropy.

It takes more coal energy to make electrical energy.

It takes more electrical energy that you get light from the light bulb.

The goal is to take low order energy that is not useful and create a higher order energy that is useful.

You have no use for coal dust but have a great need for electricity. You have no need for corn stubble but have a great need for liquid fuel.

There is a company using plasma arc to gasify garbage. They are not using governement money and they are making a profit selling their product. Their buyers are making a profit in reduced landfill cost and using the syngas to generate electricity. Right now the most feasible place in America for their technology is NYC but are having problems with corupt politicians. The mob makes alot of money in the garbage business. I personally think it would make more sense making liquid fuel instead of burning the syngas because coal is cheap and liquid fuel is expensive.


29 posted on 03/04/2007 8:02:47 PM PST by dangerdoc (dangerdoc (not actually dangerous any more))
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To: clueless123
"My dad works with the technology. It is not a hoax and I suggest that you do some research."

Agreed. We've barely scratched the surface of the possibilities of this technology.

30 posted on 03/04/2007 8:22:37 PM PST by Desron13 (If you constantly vote between the lesser of two evils then evil is your ultimate destination.)
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To: ChildOfThe60s

A few too any pills back in your teen years I see...


31 posted on 03/05/2007 2:49:17 AM PST by xcamel (Press to Test, Release to Detonate)
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