Depending on the version of the Bible you are reading, the word predestined is used 4-5 times. The word predestination is used only about 4-5 times.
Act 4:27-28 for truly in this city there were gathered together against your holy servant Jesus, whom you anointed, both Herod and Pontius Pilate, along with the Gentiles and the peoples of Israel, to do whatever your hand and your plan had predestined to take place.
The word elect is used about 15 times.
Rom_11:7 What then? Israel failed to obtain what it was seeking. The elect obtained it, but the rest were hardened,
The word chosen by God is more difficult to determine but eyeballing it is used at least 50-60 times throughout scripture.
Rom_11:5 So too at the present time there is a remnant, chosen by grace.
If you want to talk about the concept of God actively and purposely calling out a people to Himself, then you would have to include the entire scriptures for that is precisely what the nation of Israel is all about.
1Pe_2:9 But you are a chosen race, a royal priesthood, a holy nation, a people for his own possession, that you may proclaim the excellencies of him who called you out of darkness into his marvelous light.
