Romans 14:5 Some consider one day more sacred than another; others consider every day alike. Everyone should be fully convinced in their own mind. 6 Those who regard one day as special do so to the Lord. Those who eat meat do so to the Lord, for they give thanks to God; and those who abstain do so to the Lord and give thanks to God. 7 For we do not live to ourselves alone and we do not die to ourselves alone. 8 If we live, we live to the Lord; and if we die, we die to the Lord. So, whether we live or die, we belong to the Lord. 9 For this very reason, Christ died and returned to life so that he might be the Lord of both the dead and the living.
Acts 20:7 On the first day of the week we came together to break bread. Paul spoke to the people and, because he intended to leave the next day, kept on talking until midnight.
The Pope is the head of the Catholic Church.
Acts 20:7, of course, shows that Christians gathered on the first day of the week for the breaking of the bread and to hear the Word preached.
And, of course, the Resurrection itself is Scriptural ground enough to keep the first day of the week holy.