Technically, once she gets her commission, there is the possibility of transferring to any uniformed service.
I had considered it. As an Army MP Captain, I had looked into the possibility of transferring to USAF OSI. It's not common, but nor is it as rare as you may believe.
DOD INSTRUCTION 1300.04 INTER-SERVICE AND INTER-COMPONENT TRANSFERS OF SERVICE MEMBERS
Interesting, thanks.