ABSTRACT:
"Carbon dioxide in the atmosphere [historically] is the product of oceanic respiration due to the well-known but under-appreciated solubility pump. Carbon dioxide rises out of warm ocean waters where it is added to the atmosphere. There it is mixed with residual and accidental CO2, and circulated, to be absorbed into the sink of the cold ocean waters. Next the thermohaline circulation carries the CO2-rich sea water deep into the ocean. A millennium later it appears at the surface in warm waters, saturated by lower pressure and higher temperature, to be exhausted back into the atmosphere. Throughout the past 420 millennia, comprising four interglacial periods, the Vostok record of atmospheric carbon dioxide concentration is imprinted with, and fully characterized by, the physics of the solubility of CO2 in water, along with the lag in the deep ocean circulation.
Notwithstanding that carbon dioxide is a greenhouse gas, atmospheric carbon dioxide has neither caused nor amplified global temperature increases. Increased carbon dioxide has been an effect of global warming, not a cause [historically -etl]. Technically, carbon dioxide is a lagging proxy for ocean temperatures. When global temperature, and along with it, ocean temperature rises, the physics of solubility causes atmospheric CO2 to increase.
If increases in carbon dioxide, or any other greenhouse gas, could have in turn raised global temperatures, the positive feedback would have been catastrophic. While the conditions for such a catastrophe were present in the Vostok record from natural causes, the runaway event did not occur. Carbon dioxide does not accumulate in the atmosphere."
http://www.rocketscientistsjournal.com/2006/10/co2_acquittal.html
Warming causes small rises in CO2, about 10 ppm per degree of warming. The bulk of the CO2 rise can’t be explained by that (over 120ppm and rising). So fossil fuels is the next explanation and it matches all the evidence very nicely especially the quantities produced and net drop in ocean pH. We can surmise that the ocean used to release CO2 as it warmed from Little Ice Age temperatures, but now it absorbs, net.