Yup. Tektites. IIRC, there was a SciAm article about it years back.
The study of glass is actually a very interesting part of geology. Turns out every volcano produces as part of the ash, it's own very, very specific kind of glass particles.
I forget the fellows name, but he is an expert in just about every ash-producing eruption for the last 5 centuries or so... and it was his work, in part, that identified Toba as the event it was.
There's a great deal of fascinating information about obsidian here: OBSIDIAN