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Carbon dioxide sent into sea instead of into air
Contra Costa Times ^ | Sep. 09, 2006 | Robert Lee Hotz

Posted on 09/09/2006 8:53:41 AM PDT by thackney

Critics worry possible global-warming solution will alter the chemistry of underwater storage rocks, allowing gas to seep out

...

SLEIPNER PLATFORM, North Sea - Buffeted by crosswinds, the lone helicopter flew on for an hour across the shale-gray waves of the North Sea with no destination in sight.

A relief crew huddled unsteadily inside, sweating in their 20-pound immersion suits, festooned with safety whistles, buddy lines, emergency lights and inflatable life vests. Even in summer, survival in the choppy 40-degree water is measured in minutes.

Finally -- far off the coast of Norway -- the superstructure of the Sleipner platform came into view, towering 500 feet above the swell at this watery crossroads of 3,000 miles of undersea petroleum pipelines that carry natural gas for 50 million European customers.

Only one pipe led from the platform back into the seafloor. It carried industrial carbon dioxide deep into the earth from which it came.

Here, on the remote Sleipner refinery complex, the business of global warming is taking shape.

Since 1996, Norway's largest petroleum company, Statoil, has been injecting 1 million tons of carbon dioxide every year from the Sleipner complex into undersea sediments to keep the potent greenhouse gas from venting into the atmosphere.

Statoil's engineers aren't doing it to save the environment, but to save money. The Sleipner injection facility, which cost about $80 million to build, saves Statoil $53 million every year in Norwegian taxes on carbon-dioxide emissions.

For some, the Sleipner platform is a harbinger of the future of fossil fuels, in which energy companies and power utilities retool for new greenhouse-gas standards.

Although business executives generally oppose such controls, energy-company planners here believe there may be opportunities in the financial balance sheet of global warming.

Even before all of the scientific, safety and legal questions are settled, energy companies from Scotland to Southern California are gambling billions of dollars on the hope that they can meet growing demands for electricity with oil, gas and coal, and avoid the increasing financial penalties by burying the greenhouse gases they generate.

The work can be as dangerous and grueling as extracting oil.

Standing on a blue walkway inside the Sleipner platform, Tor Fjaeran, Statoil's senior vice president for the environment, braced himself against the trunk of Control Valve A-16, where a ring of 12 bolts -- each the size of a fist -- secured it to a vertical pipe channeling pressurized carbon dioxide almost half a mile underground.

Far below, 70-seat lifeboats hang nose-down in harnesses 60 feet above the water like bullets in a bandolier. In an emergency, they free-fall into the sea. Fjaeran has ridden the boats down twice during training.

"Those 2 1/2 seconds in the air ... are very long," he said.

The Sleipner platform, about 140 miles from the city of Stavanger on the Norwegian coast, is a 34,000-ton Rubik's cube of color-coded conduits, control valves and compressors.

The 240 men and women here are engaged in what the U.N.'s International Labor Organization has ranked as the world's most-hazardous employment.

The threat of a gas explosion is omnipresent.

Flash photography is banned, lest automatic sensors interpret the burst of light as a fire and instantly shut down production, at a cost of millions.

In the most severe weather, winds top 130 mph and 70-foot waves slap against the platform's concrete pilings.

The complex comprises three platforms linked by catwalks -- each a pad for the intricate network of turbines and pressure chambers required to pump and refine so much fossil fuel.

Raw natural gas comes into the platform containing as much as 9 percent carbon dioxide. To reduce the CO2 to acceptable levels, the natural gas is chemically treated in an 11-story carbon-capture unit.

Almost all energy companies vent excess gas into the air. On the Sleipner platform, however, four turbines compress the trapped carbon dioxide to 80 times the normal atmospheric pressure and inject it into a subterranean plateau of porous sandstone 2,600 feet below the seabed. This vast natural storage tank is sealed by a cap of impermeable shale 2,000 feet thick, the same oil dome that trapped the reservoir of North Sea petroleum in place for eons.

By 2050, experts estimate, carbon-capture and storage operations such as those at the Sleipner platform could account for half the reduction in CO2 needed to stabilize rising emissions in the atmosphere.

To avoid rising temperatures, climate experts say carbon dioxide emissions from fossil fuels -- which have added 152 billion tons of carbon to the atmosphere since the mid-1970s -- must be cut in half by the end of the century.

Energy demand, however, is expected to double in coming decades, much of it to be met by fossil fuels, energy analysts and climate experts say.

The North Sea aquifer could safely hold all the carbon dioxide emitted by Europe's power plants during the next 600 years, oil company researchers say. Undersea sediments along the U.S. coastline may be sufficient to store the nation's annual CO2 emissions for thousands of years, researchers at the Massachusetts Institute of Technology and Harvard and Columbia universities determined in August.

"The capacity is essentially infinite," said Harvard climatologist Daniel Schrag. "We would run out of coal long before we would run out of storage space."

The technology of injection is well known. For decades, oil companies have boosted production by raising the pressure in depleted fields with CO2 injections.

Until recently, however, nobody cared so much whether that carbon dioxide stayed put for very long.

That is starting to change. Since 2000, the North American energy company EnCana Corp. has boosted oil production 50 percent at Weyburn, Canada, by injecting millions of tons of surplus CO2 from North Dakota. Plans call for at least 20 million tons in all to be sequestered permanently there in coming decades -- an amount equal to the annual emissions of 6.8 million cars.

So far, monitoring indicates that most of it will stay underground but, by one report, about 2,500 tons a day bubble to the surface, where it must be recaptured and re-injected.

Critics of the storage operations worry about the long-term safety of the reservoirs. No one knows whether excess carbon dioxide will remain stable underground for hundreds or thousands of years.

"If it can find any well, crack or conduit in the rock, it will escape," said Harvard carbon storage researcher Kurt Zenz House.

Experts also worry how so much carbon dioxide will alter the chemistry of the storage formations themselves. Bubbles composed of millions of tons of sequestered CO2 could form an acid that could etch away the confining rocks or erode the concrete caps on well heads.

To test the effects of carbon dioxide storage, researchers funded by the U.S. Department of Energy recently injected 2,000 tons -- about half a day's power-plant emissions -- into a mile-deep well northeast of Houston.

After monitoring the site for two years, researchers at the U.S. Geological Survey found no leaks.

But in a study made public in July, they did discover that the buried CO2 increased the acidity of the saltwater in the rock enough to dissolve the surrounding minerals. Should enough minerals be eaten away, the gas could seep slowly into the atmosphere again, they reported. The acidic solution also could combine with trace metals and organic compounds to contaminate groundwater.

"We can't just dump this CO2 anywhere without knowing what is there underground and what is happening to it," said USGS scientist Yousif Kharaka, who conducted the analysis.

At Harvard, House and his colleagues believe the most effective way to store excess carbon dioxide is to sequester it offshore in ocean sediments more than 9,000 feet deep. In theory, they said, the combination of extreme pressure and severe cold would make the CO2 slurry so dense that it would sink of its own weight.

Since starting injections in 1996, Statoil technicians surveyed the carbon dioxide with 3-D seismic sensors that can track the gas as it moves through the brine-soaked rock. So far, it has stayed where they put it.

In the absence of taxes or federal regulations to encourage its use, the technology of carbon storage so far is too expensive for many power plants to adopt voluntarily, especially coal-fired plants. In the United States, CO2 emissions from the largest plants can run as high as 18 million tons annually.

But as greenhouse gases in the atmosphere reach increasingly higher levels, the need to sequester carbon dioxide safely may become a profitable enterprise.

"This is the only way for the fossil-fuel industries to survive -- to become part of the solution," said Fjaeran of Statoil.


TOPICS: News/Current Events
KEYWORDS: co2; energy; gas; oil
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1 posted on 09/09/2006 8:53:42 AM PDT by thackney
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To: thackney

Aren't they not simply putting the CO2 back into the ground from where it came? I understand they are chemically removing it from the natural gas, maybe someone who understands this can comment.


2 posted on 09/09/2006 8:56:43 AM PDT by finnman69 (cum puella incedit minore medio corpore sub quo manifestu s globus, inflammare animos)
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To: thackney

Hey moonbats-carbon dioxide IS NOT A POLLUTANT!

If you don't believe me, ask the next plant you see. You do talk to plants, don't you?


3 posted on 09/09/2006 8:58:27 AM PDT by Fresh Wind (Democrats are guilty of whatever they scream the loudest about.)
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To: finnman69

Yes, they are sending the CO2 back into the ground.


4 posted on 09/09/2006 8:59:23 AM PDT by thackney (life is fragile, handle with prayer)
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To: thackney
"If it can find any well, crack or conduit in the rock, it will escape," said Harvard carbon storage researcher Kurt Zenz House.

Harvard carbon storage researcher?
5 posted on 09/09/2006 9:00:40 AM PDT by kinoxi
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To: Fresh Wind
Anything in abundance can be a bad thing. The planet Venus might be a habitable earth-like environment were it not for an overabundance of CO2.
6 posted on 09/09/2006 9:02:00 AM PDT by free_at_jsl.com
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To: thackney

I don't wan't my oceans carbonated. I don't like bubbly water shooting up my nose!


7 posted on 09/09/2006 9:03:01 AM PDT by MAD-AS-HELL (Put a mirror to the face of the republican party and all you'll see is a Donkey.)
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To: free_at_jsl.com

I was under the impression that it was chemically different and closer to the sun.


8 posted on 09/09/2006 9:04:04 AM PDT by kinoxi
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To: Fresh Wind
What about all the dihydrogenmonoxide produced by combustion?

Shouldn't we inject that also? I've heard that this other major byproduct of hydrocarbon combustion is an even bigger threat as a greenhouse gas than CO2.

We're doomed!

9 posted on 09/09/2006 9:04:09 AM PDT by Paladin2 (If the political indictment's from Fitz, the jury always acquits.)
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To: Fresh Wind

An overabundance of oxygen in the atmosphere (be it a room or the world) will kill you. It's the balance, which humans are changing, that is being discussed. I'm just not convinced what humans are doing is enough to cause any real impact.


10 posted on 09/09/2006 9:04:33 AM PDT by Toby06
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To: Paladin2
What about all the dihydrogenmonoxide produced by combustion?

Usually we just drink it. Or put it on the plants.

11 posted on 09/09/2006 9:06:51 AM PDT by thackney (life is fragile, handle with prayer)
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To: free_at_jsl.com
O2 seems to be in great abundance. Also water vapor. CO2 seems to be several orders of magnitude lower in concentration. Would you please quit making all that CO2 yourself?
12 posted on 09/09/2006 9:07:06 AM PDT by Paladin2 (If the political indictment's from Fitz, the jury always acquits.)
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To: Toby06
Well, look here then:

http://www.geocraft.com/WVFossils/greenhouse_data.html

(Note that when using Firefox one only has to highlight and drag urls to the url box)

;-)

13 posted on 09/09/2006 9:12:02 AM PDT by Paladin2 (If the political indictment's from Fitz, the jury always acquits.)
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To: Paladin2
We're doomed!

You shouldn't joke about it. This is cereal, very cereal.
14 posted on 09/09/2006 9:21:45 AM PDT by kinoxi
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To: thackney

What a waste.


15 posted on 09/09/2006 9:26:38 AM PDT by Dan Evans
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To: kinoxi
I was under the impression that it was chemically different and closer to the sun.

About the only thing the sun and venus have in common is that they're hotter than earth. Venus is a rocky planet, about the size of our own, only with thick clouds that keep the heat in, warming the surface to 900 degrees. The sun is a thermonuclear cloud of plasma, hydrogen and helium.

16 posted on 09/09/2006 9:30:32 AM PDT by Alter Kaker ("Whatever tears one sheds, in the end one always blows one's nose." - Heine)
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To: Alter Kaker
It was in response to post #6. The Earth and Venus are chemically different as well as receiving different amounts of solar radiation.
17 posted on 09/09/2006 9:32:53 AM PDT by kinoxi
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To: Paladin2
O2 seems to be in great abundance. Also water vapor. CO2 seems to be several orders of magnitude lower in concentration. Would you please quit making all that CO2 yourself?

Yes, and large quantities of O2 are also toxic. What's your point? The same is true for lots of substances -- beneficial to a certain point, but harmful beyond that. Iodine and nickel are highly toxic, but you still need to consume a small amount to stay healthy.

18 posted on 09/09/2006 9:33:57 AM PDT by Alter Kaker ("Whatever tears one sheds, in the end one always blows one's nose." - Heine)
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To: Fresh Wind
Forty-five years ago in science class, I remember this word and the process it represents:

pho·to·syn·the·sis (ft-snth-ss) Pronunciation Key n. The process in green plants and certain other organisms by which carbohydrates are synthesized from carbon dioxide and water using light as an energy source. Most forms of photosynthesis release oxygen as a byproduct.

And, the oceans perform about 80% of this process.

19 posted on 09/09/2006 9:34:25 AM PDT by Cobra64 (All we get are lame ideas from Republicans and lame criticism from dems about those lame ideas.)
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To: Alter Kaker
I'd guess that CO2 could rise to 1% and life on Earth would still continue to function compatibly with the continued presence of Man.
20 posted on 09/09/2006 9:37:05 AM PDT by Paladin2 (If the political indictment's from Fitz, the jury always acquits.)
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