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Flour, Eggs, Sugar, Chocolate . . . Just Add Chemistry
NY Times ^ | December 28, 2004 | KENNETH CHANG

Posted on 12/27/2004 11:12:27 PM PST by neverdem

ATLANTA - With two bad knees, Shirley O. Corriher is not quite as nimble as she once was when she performs her "protein hop" - an interpretive dance of sorts to demonstrate the molecular transformations that turn flour, eggs and sugar into a cake.

Her arms wave vigorously, mimicking how proteins in wheat flour interlock to provide the structure that holds a baked good together.

"When you add water to flour and stir," she says, "these two little proteins - glutenin and gliadin - grab water first, and each other, to make these springy elastic sheets of gluten."

Ms. Corriher, who trained as a biochemist and once cooked for 140 boys in a boarding school she started with a former husband, has found a comfortable niche dispensing folksy, scientific wisdom about what really happens during cooking. Her home phone number is the 911 for chefs and cookbook authors with kitchen crises.

Susan G. Purdy, author of "The Perfect Cake" who is working on a book about baking at high altitudes, called Ms. Corriher in a panic when a chocolate cake recipe that had previously worked perfectly ended up as a chocolate puddle at 9,000 feet.

Ms. Corriher found that Ms. Purdy was using so-called Dutch-processed cocoa, treated with an alkaline substance like baking soda to produce what many consider a better, less bitter taste. Before the glutenin and gliadin proteins can clump together as gluten, they must first partly unwind and unfold, and acidity in the batter induces that unwinding.

The Dutch-processed cocoa neutralized the acidity; the glutenin and gliadin did not unwind; and Ms. Purdy's cake never solidified. Ms. Corriher had a simple solution: throw out the Dutch-processed cocoa. "It's a disaster for you," she told Ms. Purdy.

Ms. Purdy substituted natural cocoa. The cake worked.

On the other hand, too much gluten produces a chewiness that, while welcome in bread, is usually not a quality sought in a cake. That is why cake flour contains 7.5 to 8.5 percent protein, while bread flour is more protein rich, 11.5 to 12.5 percent. (All-purpose flour is somewhere in between and thus not ideal for either use.)

Cooking is often taught as a step-by-step progression of instructions or an art learned through some nebulous communion with the ingredients, but it is also chemistry, predictable, repeatable molecular reactions brought about by mixing ingredients - which are, after all, chemicals - and applying heat to them.

Ms. Corriher's 1997 book, "CookWise: The Hows and Whys of Successful Cooking, " brought such scientific facts to home cooks, and although the first 150 pages of the book discuss baking, her publisher wanted a sequel devoted entirely to baking. The publisher gave her three years to deliver the manuscript. Today, four years after her deadline, Ms. Corriher is still working on the book, to be titled "BakeWise."

For the last two years, she has been stuck on the cake chapter.

"She's - how should we say it? - a very thorough writer," said her friend Harold McGee, author of "On Food and Cooking."

For example, Ms. Corriher performed an experiment on sifting. Many recipes call for sifting to mix flour with the other dry ingredients, and it is especially important to disperse the leavener - typically, baking powder - so that a cake rises evenly.

So Ms. Corriher took a black powder with roughly the same characteristics as baking powder and sifted it with flour.

Sifting, it turns out, is not particularly effective.

"You just didn't get a good mix, even after three or four times," Ms. Corriher said. "You can see little dark streaks."

Simply stirring the dry ingredients together with a wooden spoon is better, she said.

The other historical need for sifting was to fluff up the flour after it had been compacted during shipping, but that is also no longer necessary, because flour, sifted at the factory, is now shipped in individual packages instead of large barrels and is not crushed as much.

Contributing to the delay, Ms. Corriher has also not been able to stop herself from making yet another variation of a familiar cake recipe, in search of yet one more refinement.

"Oh, I've been making cakes and making cakes and making cakes and making cakes," she said. "I end up making five or six or seven cakes testing out things that I think up."

Last year, she and her husband, Arch Corriher, ate more pound cakes than they could remember.

The traditional pound cake got its name because it contained a pound of flour, a pound of sugar, a pound of eggs and a pound of butter. That was also a large cake, so modern day recipes usually cut those quantities in half. It is also a fairly dense, dry cake.

Bakers over the years have improved the traditional pound cake by adding other ingredients: buttermilk or sour cream to make it moister, baking powder to make it airier.

Ms. Corriher has her own wrinkles to the recipe, substituting cooking oil for part of the butter - that greases the wheat proteins, producing less gluten and leaving more moisture for the cake - and potato starch for some of the flour. Potato starch granules are considerably longer than the starch granules found in wheat flour. "It really absorbs water like crazy," Ms. Corriher said. "And it makes things really moist."

(Potato starch is not a panacea for all cakes. When she tried potato starch in a basic white cake, the result was grainy. "It was awful, awful, awful," Ms. Corriher said, recoiling at the memory. "Life goes on.")

While her pound cake was delicious, Ms. Corriher was not satisfied, because it sagged when baked in a loaf pan. She tried more variations, like additional flour, to produce an attractive, domed top, but those turned out drier. "Of course, the one with too much butter and sugar is going to taste better," she said.

Finally, she decided the solution was to bake the pound cake in a Bundt or tube pan, so that the shape of the pan held the cake together. "The moral of the story is, Here is a cake that is technically wrong," Ms. Corriher said, "but the taste is great."

Taking the destabilizing effects of sugar to an extreme is the tunnel-of-fudge cake. "It is so deadly, you can't believe how deadly it is," she said. "We are deliberately doing a cake with way too much sugar."

Sugar, she explained, binds to the flour proteins, preventing them from forming the structural lattice. "Glutenin runs off with sugar," Ms. Corriher said. "Gliadin runs off with sugar, and you don't get much gluten."

When baked, the outer portions reach a high enough temperature that they harden, but the cooler inner part remains soft and gooey.

"We've eaten a whole cake, the two of us," Ms. Corriher said.

Her husband interjected, "Over a period of time."

"It was a very brief period of time," Ms. Corriher said. "It's very addicting."

"It's really rich," Mr. Corriher said.

"And wonderful," Ms. Corriher added.

The original tunnel-of-fudge cake won second place in the 1966 Pillsbury Bake-Off Contest for Ella Rita Helfrich of Houston. That version used a fudge icing mix to create a gooey chocolate center. But Pillsbury discontinued the icing mix, and the resulting clamor of home bakers led Pillsbury to release a recipe for making tunnel-of-fudge cake from scratch.

Ms. Corriher again applied her standard tricks, substituting two yolks for one of the eggs, substituting oil for part of the butter. In addition, she substituted dark brown sugar for some of the white sugar. "The reasoning there is dark brown sugar brings out a fudgy taste in chocolate," she said.

She also roasted the nuts. "You get much more flavor," she said. "You know how much better a roasted nut tastes than a plain old raw nut."

Dutch-processed cocoa in a tunnel-of-fudge cake would probably spell disaster, preventing even the outside of the cake from setting, she said.

Ms. Corriher said she had learned much about cakes by making one that leaves out one of usual ingredients. "You really learn what flour does and what eggs do," she said.

A chocolate cake called crazy cake leaves out the eggs. Ms. Corriher suspects it dates to World War II when staples like eggs were rationed.

Without the egg proteins, which also help a cake hold together, gluten is essential for the cake to hold its shape. Thus, cake flour, with its lower protein levels, will not work for crazy cake.

Ms. Corriher improved the recipe by cutting down on the vinegar - needed to make the batter acidic - and the leavener, but she hit a snag when she tried adding buttermilk to make it moister. The resulting cake remained pudding. That led to a debate with Harold McGee about why the cake did not set. She thought that the buttermilk was affecting the acidity. Mr. McGee thought the milk proteins were preventing the flour proteins from holding together.

Mr. McGee was correct. When she added more flour, the cake again set. Milk proteins differ from egg and flour proteins in that they do not coagulate, Mr. McGee said. "You can boil milk for hours and it doesn't set," he said, "whereas if you boil an egg for 20 seconds, it turns into a solid."

Milk solidifies - into yogurt or cheese, for instance - only if it has been treated with an enzyme that knocks off part of the proteins, making them more like other proteins.

Meanwhile, Ms. Corriher said she wanted to finish "BakeWise" within a few months. She thinks that maybe it will even be in bookstores by next Christmas. "I really think I'm on the homestretch on the cake chapter," she said.


TOPICS: Culture/Society; News/Current Events
KEYWORDS: cakes; chemistry; scienceeducation
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Robin Nelson/ZUMA
Shirley O. Corriher, experimenting with a tunnel-of-fudge cake.


1 posted on 12/27/2004 11:12:28 PM PST by neverdem
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To: neverdem

As my dear Grandma would have said, "Oh. Just shutup and eat".


2 posted on 12/27/2004 11:17:18 PM PST by Fiddlstix (This Tagline for sale. (Presented by TagLines R US))
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To: neverdem

I think this lady has been on "Good Eats" on the Food Network. Even if you don't want to cook whatever Alton is talking about, there's usually some good tongue in cheek babble or food science to enjoy.


3 posted on 12/27/2004 11:32:59 PM PST by GnuHere
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To: neverdem

As much as I've always adored Ms Corriher, (and cooking) I guess I don't understand how she or cooking lessons fit onto a political action website.


4 posted on 12/27/2004 11:54:41 PM PST by Awestruck (The artist formerly known as Goodie D)
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To: Awestruck
As much as I've always adored Ms Corriher, (and cooking) I guess I don't understand how she or cooking lessons fit onto a political action website.

Christmas Dinner Leftovers...Who's Hungry?

comment 20 of 191

My father in law brought some excellent tamales and luckily there are leftovers, as well as his roast goose and goose gravy (the most amazing stuff!).. my Christmas potatoes are all gone unfortunately, but lucky for me I still have pilaf and duck. And of course cookies and candy enough to make a small army sick.

I guess political action is your only interest, huh?

5 posted on 12/28/2004 12:22:00 AM PST by neverdem (May you be in heaven a half hour before the devil knows that you're dead.)
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To: El Gato; JudyB1938; Ernest_at_the_Beach; Robert A. Cook, PE; lepton; LadyDoc; jb6; tiamat; PGalt; ..

FReepmail me if you want on or off my health and science ping list.


6 posted on 12/28/2004 12:23:48 AM PST by neverdem (May you be in heaven a half hour before the devil knows that you're dead.)
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To: GnuHere
Yes, she's on Good Eats pretty regularly. A great show -- part Galloping Gournet, part Dr. Science, with a little MST3K thrown in.
7 posted on 12/28/2004 12:35:11 AM PST by inkling
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To: neverdem

This is the lady on Alton Brown's Good Eats show.

My kind of thread! Thanks :-)


8 posted on 12/28/2004 12:40:22 AM PST by Canticle_of_Deborah
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To: neverdem

But I want a crunchy surface on my tunnel of fudge cake! ;)

I envy authors who've reached the type of status where they can take -- and can afford to take! -- years to write a book.


9 posted on 12/28/2004 1:52:30 AM PST by Fawnn (Canteen wOOhOO Consultant and CookingWithPam.com person - Faith makes things possible, not easy.)
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To: 2Jedismom

ping!


10 posted on 12/28/2004 5:12:35 AM PST by Lil'freeper (Error 404. The page you requested was not found.)
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To: Lil'freeper
Heh!! You remember my husband's birthday cake from last year?? What a disaster.

I'd rather make bread. Gluten was the best thing I ever discovered for making bread!

11 posted on 12/28/2004 5:26:54 AM PST by 2Jedismom (FMM)
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To: 2Jedismom

Looks like that cake belongs here:
Gallery of Regrettable Food
http://www.lileks.com/institute/gallery/index.html

After you enjoy Lileks Institute of Official Cheer, check out his blog.


12 posted on 12/28/2004 5:48:34 AM PST by brewer1516
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To: neverdem

I LOVE having this data!


13 posted on 12/28/2004 6:26:36 AM PST by GVnana (If I had a Buckhead moment would I know it?)
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To: 2Jedismom

Yikes! Of course, the main question is, did it taste good?

If so, who cares what it looked like (c;


14 posted on 12/28/2004 7:04:06 AM PST by Darnright
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To: GnuHere
I think this lady has been on "Good Eats" on the Food Network.

Yes, Shirley is a regular on the show.

I never thought I'd watch a cooking show regularly, but "Good Eats" has me hooked. It's very innovative.

15 posted on 12/28/2004 7:13:34 AM PST by Semi Civil Servant
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To: neverdem

no, of course not, but then again, I didn't POST the story, did I? I was asking a valid question, no need to get defensive. Forgive me if I offeneded.


16 posted on 12/28/2004 10:16:26 AM PST by Awestruck (The artist formerly known as Goodie D)
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To: Awestruck
I was asking a valid question, no need to get defensive.

I am more curious than defensive. Why didn't the previous thread that referenced your comment about Christmas eating reflect a similar attitude from you? What does Christmas eating have to have to do with a political action website?

I guess I don't understand how she or cooking lessons fit onto a political action website.

The chemistry is what I wanted to illustrate. If you noticed I have a health and science ping list. More and more political questions require an understanding of basic science. That some folks enjoy pastries was a secondary benefit. Happy New Year!

17 posted on 12/28/2004 11:02:15 AM PST by neverdem (May you be in heaven a half hour before the devil knows that you're dead.)
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To: neverdem

Probably because at the time I was deeply entrenched in the Christmas spirit, and now have hit the downside of that..forgive me, you were the unintended victim of my post Christmas crabbiness...


18 posted on 12/28/2004 12:45:24 PM PST by Awestruck (The artist formerly known as Goodie D)
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To: neverdem

I'm sorry. That might taste good, but a cake that's called "tunnel of fudge" and looks like that picture...ewww.


19 posted on 12/28/2004 12:47:00 PM PST by Dooderbutt
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To: Darnright
Of course, the main question is, did it taste good? If so, who cares what it looked like

Heathen! Have you never heard of "presentation"?

(Of course, I decorate cakes as a hobby, so I may be just a tiny bit biased on the subject...)

20 posted on 12/28/2004 12:48:46 PM PST by kevkrom (If people are free to do as they wish, they are almost certain not to do as Utopian planners wish)
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