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Sun and hydrogen 'to fuel future'(hydrogen fuel cell)
BBC NEWS ^ | 08/12/04 | Jo Twist

Posted on 08/13/2004 6:57:00 PM PDT by TigerLikesRooster

Sun and hydrogen 'to fuel future'

By Jo Twist
BBC News Online science and technology staff

Turning sunlight into hydrogen could be the future

Capturing sunlight to make enough hydrogen fuel to power cars and buildings has been brought a step closer by a British research company.

Hydrogen Solar says it has managed to convert more than 8% of sunlight directly into hydrogen with fuel cell technology it has specially developed.

For an energy source to be commercially viable, it must reach an efficiency of 10%, which is an industry standard.

Hydrogen power, a renewable energy, has the potential to replace fossil fuels.

"Over the last couple of years we have doubled efficiency.

"We are not yet in the hydrogen economy, but it has the potential to take over when the oil economy becomes untenable," Dr David Auty, chief executive of Hydrogen Solar told BBC News Online.

Nano hand

Depending on how it is produced, hydrogen fuel is a clean, green source of power that can be easily stored.

Its potential has been recognised for well over 100 years, but it requires energy to extract hydrogen from

water, or any other source.

The Tandem Cell technology developed by Hydrogen Solar uses two photocatalytic cells in series which are coated with a nano-crystalline - extremely thin - metal oxide film.

Having a nanoscale coating makes the surface area far greater and means that hydrogen can be produced efficiently without the need for polluting fossil fuels.

The cells capture the full spectrum of ultraviolet light - the Sun's rays - and, via the novel coating, the electrons are captured and carried away on conductors.

1 Ultraviolet sunlight passes through glass skin of cell
2 Light is captured in glass coated with nano-crystalline film
3 Nano-coating properties enable the glass to conduct electricity, which is used to separate the water into oxygen and hydrogen
4 Hydrogen gas is stored for later use as a power source

This electrical current is then used to separate the hydrogen from water which is stored for use.

The key to the process has been the advances in novel coatings brought about by recent developments in nanotechnology.

A car could run for 11,000 miles on hydrogen

The size of the molecules in the coating is 15 to 20 nanometres (a nanometre being a billionth of a metre).

When they are stacked in layers, the property of the substance changes to produce large surface areas.

"It turns out these devices work because we are using nanocrystalline layers. It is the move to nanotechnology which has brought this technology forward," explained Dr Auty.

He added: "If we look five years ahead and we have a few square miles of hydrogen farm in a desert, we think we could produce hydrogen that is competitive with coal and oil."

Once production costs have been scaled down, large hydrogen cell farms could produce hydrogen, untaxed, at $1.80 to $3 a kilo.

That is equivalent to a third of the price of the same amount of power produced from untaxed gasoline, he thinks.

There has been huge amount of work in fuel cells for buses, cars, houses, and other buildings.

But Dr Auty envisages the car industry making the best use of the technology in modified combustion engines.

"Using a 10% cell, we say that a seven-metre squared array will power a Mercedes A class car for 11,000 miles a year [in LA sunlight conditions] without going to power station," said Dr Auty.

Motor future

Hydrogen power has also be produced from hydrocarbons, like oil and gas, but these have downsides in their byproducts.

Pollution-free hydrogen cell technology is predicted to be the next wave in emissions-control after the hybrid electric motor, currently used in the automotive industry.

Research into hydrogen power has been pumped with funding in the US in particular.

In 2003, President George Bush announced an $1.7bn investment to turn the US into the world leaders of hydrogen-powered automobiles.

With increasing concern about the instability of the oil market, the development of a commercially viable alternative energy source has attracted interest.

"The potential lack of oil is the reason we are doing this," Dr Auty said.

"There are huge amounts of carbon released through coal and other hydrocarbons."

Last year, General Motors (GM) said it planned to be the first to sell a million fuel cell vehicles in the next decade.

Other automotive giants have also championed hydrogen fuel.

DaimlerChrysler, Ford and GM have spent about $2bn on fuel cell cars, trucks and buses. The first products came out last year, and many UK cities have deployed hydrogen buses.

Ford's Chairman William Clay Ford Jr went so far as predicting fuel cells would end the reign of the internal combustion engine.

But there have been a number of technical and financial stumbling blocks - including taxation - which have prevented its large scale adoption, and Dr Auty thinks there need to be more political will to push the technology forward.

"There is a chicken and egg issue here," he said.

"Who is going to build a car before they have filling stations, and who is going to build stations before we have the cars.

"It has to be strategically thought out and driven by government. There is a political will in US, but I think the UK is a bit behind the pace."

"The key about all of this is that all predictions about crude oil are pretty much going to be in our lifetimes," said Dr Auty.

"But if you talk about infrastructure change, these things don't happen overnight."



TOPICS: Business/Economy; Foreign Affairs; Front Page News; News/Current Events
KEYWORDS: energy; fuelcell; hydrogen; nanotech; oil; sunlight
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To: TigerLikesRooster

The technology's only at 8% efficiency. It requires 10%.

Question: Why the missing 2%?

Answer: Haliburton.


21 posted on 08/13/2004 8:31:45 PM PDT by samtheman (www.georgewbush.com)
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22 posted on 08/13/2004 8:37:14 PM PDT by jla (http://www.ronaldreaganmemorial.com/memorial_fund.asp)
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To: TigerLikesRooster

These technologies are as overhyped as the incessant predictions of the demise of hydrocarbon energy is mistaken.


23 posted on 08/13/2004 9:28:11 PM PDT by B.Bumbleberry
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To: nightdriver

A more efficient solar cell would be fairly revolutionary in itself. As it stands right now, if you currently pay $.11 or more per kilowatt hour then solar is already cost competitive. That means that for most of us it's still cheaper and easier to rely on the electric company, but if they can bring the costs of the panels down and improve their efficiency enough solar power will become the cheapest way for most homeowners to get their electricity.


24 posted on 08/13/2004 10:30:23 PM PDT by elmer fudd
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To: RightWhale

Is hydrogen a volatile medium? Think Hindenberg. Think Hindenberg exploding.



Think Hindenberg, but think right. The hydrogen did not explode, it didn't even start the fire.


Hate to be disagreeable but my text books describe hydrogen as volatile and extremely flammable. Hydrogen was the element used in the German Hindenberg and other zeppelins. I haven't read the reports from the Lindhurst, NJ crash site recently but the hydrogen DID explode. Maybe you're thinking of helium used in US Navy/US civilian blimps which is an element that does not explode.


25 posted on 08/13/2004 10:36:29 PM PDT by sully777 (Our descendants will be enslaved by political expediency and expenditure)
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To: GSlob; AFPhys; chipengineer; TigerLikesRooster
8 “At sun radiation at 1 KW/m2 at 10% efficiency the 7m2 cell would provide 700W=1hp during daylight.”

1.   Your estimate of available solar energy is far too generous.

  SOURCE
LOSS
(%)
POWER
(W/m2)
  1.     solar constant       --   1370W
2.   atmospheric loss       27   1000W
3.   cloud loss       21     790W
4.   sun angle loss1       50     395W
5.   night time loss2       50     198W
6.   cell conversion loss       90       20W
Source Notes:
1.   Average for hour-angle, season and latitude (37º N). Increased
      atmospheric path length was not considered.
2.   See link. Continental U.S. average sunshine is 4.8 kilowatt-hours/
      square meter/day, or 200 watts/square meter. That value is nearly
      identical with total losses shown for items 1-5 above.

2.   I realize the syntax used by the author was questionable, but since he spoke of "a seven-metre squared array", rather than "a seven square meter array", I feel pretty confident that the intended meaning was 49 square meters.

3.   In testing the reasonableness of the author's energy claims, you can avoid any question or discussion about the automobile's horsepower (whether maximum rated horsepower or operating horsepower) simply by employing the following reasoning.

gallons of gasoline saved per year
(11,000 miles @ 30 per gallon)
367 gallons
energy per gallon 120E6 Joules
total energy savings per year 44E9 Joules
energy savings per second
(Watts)
1,400 Watts
energy per second per square meter of fuel cell array 28 Watts
solar energy available per sq meter
(see above table)
20 Watts

In other words, Dr. Auty's claim that "a solar powered fuel cell array of 49 square meters that is 10% efficient, would produce enough energy to drive an automobile 11,000 miles", is fairly close to reality.

HOWEVER, WHAT IS NOT CLOSE TO REALITY is some of the related claims and fuel cell requirements.

First, according to the article, the conversion process relies on solar ultraviolet radiation, but since UV comprises less than 10% of the total solar radiation, how can he have a cell that is 10% efficient???

Second, there is no such thing as a low price glass that is highly transparent to UV radiation. Just how economic a process will this be when it requires acre upon acre of amorphous quartz (or something equally expensive)?

Third, based on my experience, I would be extremely surprised if they can make such an array cheaper than solar cells (which are not an economically viable source of energy) and those run in the neighborhood of $500 to $1000 per square meter.

If you got lucky and got an 8% interest only loan to pay the cost of capitalizing Dr. Auty's contraption, the fuel cost would not be the $1.80 to $3.00 per liter that Dr. Auty claimed, but rather it would be about $6.24 to $12.47 per liter. (The number of liters per year equals 44E9 J divided by 140E6 J per liter of H2. At a cost of $500 per square meter, capitalization cost for 49 square meters of fuel cell would be $24,500 and the annual interest would be $1,960.)

There is only one way that Dr. Auty's scheme can be made to be economically viable. If you can't lower your own costs, you've got no alternative but to cause your competitors prices to rise. And you do that through government interference with the free market place.

Raise the gas tax, raise the road use tax, and do it both at the state and federal levels. Restrict new drilling for oil. Institute ever more restrictive environmental controls. Don't allow new refineries to be built. Require the use of oxygenated fuels. Institute a carbon tax.

Oh, wait, we're already doing that! Welcome home Dr. Auty, your time has finally come.

--Boot Hill

26 posted on 08/14/2004 5:28:02 AM PDT by Boot Hill (Candy-gram for Osama bin Mongo, candy-gram for Osama bin Mongo!!!)
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To: Boot Hill
RE #26

Thanks for your informative discussion.:)

27 posted on 08/14/2004 7:52:05 AM PDT by TigerLikesRooster
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To: Boot Hill

By the time this type of energy is perfected, someone will find a different way.


28 posted on 08/14/2004 8:34:26 AM PDT by US_MilitaryRules (To All dimocrats,"Would you have wished your mother was pro choice"?)
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To: plangent

Yes and in order to start a business you have to spend allot of money up front... When the technology reaches higher effecincies you can you it to power the process of makin the cells... Its a ways off but dont dismiss it..


29 posted on 08/14/2004 8:48:33 AM PDT by N3WBI3
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To: sully777
Maybe you're thinking of helium

Can 50 million Frenchmen be wrong?

30 posted on 08/14/2004 9:13:41 AM PDT by RightWhale (Withdraw from the 1967 UN Outer Space Treaty and establish property rights)
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To: TigerLikesRooster
“Thanks for your informative discussion.”

You're welcome, but there was an error in the forth paragraph from the bottom of my post that I correct below.

“If you got lucky and got an 8% interest only loan to pay the cost of capitalizing Dr. Auty's contraption, the fuel cost would not be the $1.80 to $3.00 per kilogram that Dr. Auty claimed, but rather it would be about $6.24 to $12.47 per kilogram. (The number of kilograms per year equals 44E9 J divided by 140E6 J per kilogram of H2. At a cost of $500 per square meter, capitalization cost for 49 square meters of fuel cell would be $24,500 and the annual interest would be $1,960.)”
In addtion to what I posted in my earlier post, another pitfall to Dr. Auty's fuel cell idea is with the tank that would be necessary to carry the liquid hydrogen. In his example of using this hydrogen to power an automobile, a 12 gallon gasoline tank would weigh about 20 pounds, but a tank for LH would have to hold 45 gallons, to provide the same mileage capacity, and the empty weight of this LH tank would be close to 400 pounds and would be bigger than a 55 gallon drum! (Look at your own car and try to figure where you could hide a 55 gallon drum!)

--Boot Hill

31 posted on 08/14/2004 6:46:52 PM PDT by Boot Hill (Candy-gram for Osama bin Mongo, candy-gram for Osama bin Mongo!!!)
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To: Boot Hill

Hydrogen will be carried in an absorptive material inside a tank. Neither high pressure nor cryogenic tanks will be needed.


32 posted on 08/14/2004 10:17:26 PM PDT by RightWhale (Withdraw from the 1967 UN Outer Space Treaty and establish property rights)
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To: TigerLikesRooster

bump


33 posted on 08/14/2004 10:21:26 PM PDT by fso301
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To: RightWhale
“Hydrogen will be carried in an absorptive material inside a tank.”

I addressed the issue of storage as a gas because the article only spoke of that means of storage.

Nevertheless, there is no weight or volume advantage to storing hydrogen in another material. No matter the material you use, you will either drastically increase weight, volume or (more likely) both.

For example (since you didn't identify any specific material), here is what happens when you use a metal hydride as a storage medium for hydrogen:   The metal hydride storage will be 20 times heavier and nearly 3 times the volume than an equal energy-quantity of gasoline.

In the example using a 12 gallon gasoline tank, that means your fuel would now weigh more than 1,500 pounds! You'd be better off sticking with the high pressure tanks (gag)!

--Boot Hill

34 posted on 08/15/2004 2:09:05 AM PDT by Boot Hill (Candy-gram for Osama bin Mongo, candy-gram for Osama bin Mongo!!!)
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To: nightdriver

Actually there is a more efficient solar cell being developed utilising the photsynthesis model found in ... of all things spinach. It seems that our current crop of biochemists have discovered that the photosynthesis that occurs in the spinach leaf is the most efficient known.


35 posted on 08/15/2004 2:17:40 AM PDT by Spacetrucker (Always Faithful ... then burn 'em to the ground!!)
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To: Spacetrucker
“Actually there is a more efficient solar cell being developed utilising the photsynthesis model found in ... of all things spinach.”

I think you may have been mislead by an over-reaching "science" reporter. One of the least attractive aspects of the spinach powered bio-solar cells is their efficiency. Even theoretical efficiencies are an order of magnitude below the common silicon solar cell.

--Boot Hill

36 posted on 08/15/2004 2:48:35 AM PDT by Boot Hill (Candy-gram for Osama bin Mongo, candy-gram for Osama bin Mongo!!!)
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To: Boot Hill

Quite possible - I have never been much of a science (in the /bio/chem field) buff although the "quip" i was referring to seemed quite intriguing.


37 posted on 08/17/2004 6:21:58 AM PDT by Spacetrucker (Always Faithful ... then burn 'em to the ground!!)
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