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If the origional substance was known it would have been a snap. Cornstarch or cornmeal to absorb the excess grease. Mayo as an emulisfier will displace the oil of the peanut butter and then follow with shampoo.

As it turned out, there was no original substance. He initially lied about that in an effort to spare himself even more ridicule. He was trying to use the peanut butter as a substitute for his hair "goop." He was desperate because he wanted to hold his comb-over in place.

Origional substance was peanut butter.

I once had a teenager call me with application of surgiwax ( the stuff women use to wax their legs and bikini areas)
to his entire head of fairly long hair. He wanted the shaved look without shaving.

I was tempted to tell him something like twist it into a wick and light it but good judgement won out. If he was stupid enough to use the wax in the first place he just might follow a smart a$$ suggestion. Law suit flashed infront of my eyes.

I told him to use a hair dryer on warm to soften and then peel it in sections.