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Scientists Find New Way To Store Hydrogen Fuel
Science Daily.com ^ | January 7, 2004 | University Of Chicago

Posted on 01/07/2004 3:42:28 PM PST by aculeus

University of Chicago scientists have proposed a new method for storing hydrogen fuel in this week's online edition of the Proceedings of the National Academy of Sciences.

The lack of practical storage methods has hindered the more widespread use of hydrogen fuels, which are both renewable and environmentally clean. The most popular storage methods-liquid hydrogen and compressed hydrogen-require that the fuel be kept at extremely low temperatures or high pressures. But the University of Chicago's Wendy Mao and David Mao have formed icy materials made of molecular hydrogen that require less stringent temperature and pressure storage conditions.

"This new class of compounds offers a possible alternative route for technologically useful hydrogen storage," said Russell Hemley, Senior Staff Scientist at the Geophysical Laboratory of the Carnegie Institution of Washington. The findings also could help explain how hydrogen becomes incorporated in growing planetary bodies, he said.

The father-daughter team synthesized compounds made of hydrogen and water, hydrogen and methane, and hydrogen and octane in a diamond-anvil cell, which researchers often use to simulate the high pressures found far beneath Earth's surface.

The hydrogen-water experiments produced the best results. "The hydrogen-water system has already yielded three compounds so far, with more likely to be found," said Wendy Mao, a graduate student in Geophysical Sciences at the University of Chicago.

The compound that holds the most promise for hydrogen storage, called a hydrogen clathrate hydrate, was synthesized at pressures between 20,000 and 30,000 atmospheres and temperatures of minus 207 degrees Fahrenheit. More importantly, the compound remains stable at atmospheric pressure and a temperature of minus 320 degrees Fahrenheit, the temperature at which liquid nitrogen boils.

"We thought that would be economically very feasible. Liquid nitrogen is easy and cheap to make," Wendy Mao said.

The hydrogen in a clathrate can be released when heated to 207 degrees Fahrenheit. The clathrate's environmentally friendly byproduct: water.

David Mao noted that while petroleum-based fuels will eventually run out, the supply of hydrogen is limitless. "Hydrogen is the most abundant element in the universe," said David Mao, a Visiting Scientist in Geophysical Sciences at the University of Chicago. If the new method of storing hydrogen fuel works as expected, "that's going to change everyone's life in a big way," he said.

The Maos have applied for a patent on their hydrogen clathrate synthesis technique, but one problem still remains: how to make the clathrates in quantities sufficient to power a car. "We've only made them in very small amounts in diamond-anvil cells," Wendy Mao said. The Carnegie Institution's Hemley noted that the clathrates can be produced in gas pressure devices as well as diamond-anvil cells.

In the realm of planetary science, the study helps explain how some of Jupiter's moons could have incorporated hydrogen during their formation. Scientists once thought that the moons were incapable of retaining hydrogen during their formation. Now it appears that Callisto, Ganymede and especially Europa contain large quantities of water ice, which would require the presence of hydrogen. The hydrogen clathrates that the Maos synthesized in the laboratory could have formed naturally under the temperature and pressure conditions expected to prevail inside these Jovian moons, Wendy Mao said.

This story has been adapted from a news release issued by University Of Chicago


TOPICS: Business/Economy; Culture/Society; Extended News; News/Current Events; US: Illinois
KEYWORDS: energy; fuelcell; hydrogen
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1 posted on 01/07/2004 3:42:29 PM PST by aculeus
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To: aculeus
Hey, any discovery that weans us away from Arab oil can only be a good thing.
2 posted on 01/07/2004 3:47:03 PM PST by Viking2002
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To: All
If you don't make a donation to Free Republic, then that's one more thing you have in common with Patrick Leahy.

3 posted on 01/07/2004 3:48:00 PM PST by Support Free Republic (Freepers post from sun to sun, but a fundraiser bot's work is never done.)
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To: Carry_Okie; RadioAstronomer
ping
4 posted on 01/07/2004 3:54:09 PM PST by farmfriend ( Isaiah 55:10,11)
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To: aculeus
America's garages are well-supplied with mechanics who can screw up a drum brake job; imagine what they'll be able to do with a tank of cryogenic (or semi-cryogenic) hydrogen!
5 posted on 01/07/2004 3:55:58 PM PST by Grut
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To: aculeus
David Mao noted that while petroleum-based fuels will eventually run out, the supply of hydrogen is limitless. "Hydrogen is the most abundant element in the universe," said David Mao, a Visiting Scientist in Geophysical Sciences at the University of Chicago. If the new method of storing hydrogen fuel works as expected, "that's going to change everyone's life in a big way," he said.

Maybe, but most of the hydrogen is already burned. That is, it's in water. It takes energy from something else (fossil fuels, nukes, the sun, whatever) to get hydrogen fuel to store. Storage is in fact the small part of the problem.

6 posted on 01/07/2004 4:01:29 PM PST by VadeRetro
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To: VadeRetro
DC current breaks down water into H and O2 .Fire up the California windmills and let loose the hydrogen tidal wave .
7 posted on 01/07/2004 4:04:56 PM PST by Renegade
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To: VadeRetro
Technically, storage of energy for use as a vehicle fuel (or a battery) is the difficult problem, if your objective is to replace petroleum fuels/carbon emissions.

Energy generation from nuclear is very well understood and economically feasible.
8 posted on 01/07/2004 4:06:29 PM PST by buwaya
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To: Viking2002
I recall when Bush announced his hydrogen-car initiative, there were a lot of mockers and nay-sayers in here. We're not there yet, but one step at a time technology moves forward, and yesterday's impossibility eventually becomes tomorrow's everyday reality.
9 posted on 01/07/2004 4:07:26 PM PST by Steve_Seattle ("Above all, shake your bum at Burton.")
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To: Renegade
DC current breaks down water into H and O2 .

Indeed it does. The problem is that it takes more energy to separate the hydrogen from the oxygen than you get back when you burn the hydrogen in oxygen to make water. Thus Mao somewhat overstates the impact of hydrogen as fuel. It's cleaner burning than fossil fuels, except you still have to burn fossil fuels or something else to make it.

10 posted on 01/07/2004 4:09:00 PM PST by VadeRetro
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To: buwaya
Technically, storage of energy for use as a vehicle fuel (or a battery) is the difficult problem, if your objective is to replace petroleum fuels/carbon emissions.

However much hydrogen you make, you're still going to burn that much fossil fuel, unless the producing region's electricity is supplied by a nuke plant. Some are, many aren't. Most of the nuke plants are old. It's been hard to start new ones since Three Mile Island, Chernobyl, and various lib scare campaigns.

11 posted on 01/07/2004 4:12:30 PM PST by VadeRetro
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To: VadeRetro
Solar, Hydro or Wind Generators can make Hydrogen. But for now they hardly meet our demands. Thus you are right any energy used to make hydrogen means more fossil fuels burned. An automobile is more efficient run on gas than hydrogen created with oil generated electricity.

I don't see why people see anything in hydrogen. Until we are off fossil fuel for electricity then it is meaningless to use hydrogen for fuel.
12 posted on 01/07/2004 4:20:35 PM PST by ImphClinton
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To: VadeRetro
Can't they, if they burn fossil fuel in a central plant and distrubute hydrogen for single-point use, put extra envirogear on the combustion process so overall it is cleaner than now?
13 posted on 01/07/2004 4:23:02 PM PST by RightWhale (Repeal the Law of the Excluded Middle)
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To: ImphClinton
That depends on the amount of useable energy stored vs. mass and volume, safety, cost, etc. Fuel for vehicles has different requirements than fuel for power plants. That's why you don't see coal-fired passenger sedans, or rocket-propelled ones for that matter.
14 posted on 01/07/2004 4:25:40 PM PST by Thud
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To: RightWhale
Can't they, if they burn fossil fuel in a central plant and distrubute hydrogen for single-point use, put extra envirogear on the combustion process so overall it is cleaner than now?

I'm sure there are efficiencies of scale if most cars are burning hydrogen. Whether that's a revolutionary advance is a question.

15 posted on 01/07/2004 4:28:36 PM PST by VadeRetro
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To: VadeRetro
Well, I said technically.

If push comes to shove there is no technical breakthrough needed to start building many new nuclear plants, or even breeder reactors.

Whether there is a good economic or public policy reason to do this is another matter.

Hydrogen powered vehicles, just like electric cars, are poor economic alternatives to hydrocarbon fuels.
16 posted on 01/07/2004 4:30:27 PM PST by buwaya
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To: buwaya
If push comes to shove there is no technical breakthrough needed to start building many new nuclear plants, or even breeder reactors.

I wish we hadn't lost our nerve in this area. We could build safer reactors today than ever before if we dared.

17 posted on 01/07/2004 4:34:34 PM PST by VadeRetro
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To: Steve_Seattle
I am still waiting on my

Mr. Fusion

18 posted on 01/07/2004 4:41:33 PM PST by joesnuffy (Moderate Islam Is For Dilettantes)
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To: VadeRetro
I wish we hadn't lost our nerve in this area. We could build safer reactors today than ever before if we dared.

During last pres election, Bush said he would push for new nuke plants. I've heard a few things about his effort, but he's been kinda busy. Nothing to show for it yet.

I think the world might soon be ready for more nukes. Particularly some of the new designs that are impossible to china syndrome.

On a bet, I recently donated to my first environmental group. The "Environmentalists for Nuclear Energy". They're based in france, but trying to fire up groups here in the US.

19 posted on 01/07/2004 4:43:36 PM PST by narby (McGovern lost in 72 - and launched the left's takover of the Dem party)
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To: joesnuffy
Mr. Fusion

I get this idea that fusion is a pipe dream that will never happen. At least right now, it appears it's only used by scientific professionals to get government grants.

20 posted on 01/07/2004 4:45:16 PM PST by narby (McGovern lost in 72 - and launched the left's takover of the Dem party)
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