Personally, Janeway always struck me as the one who’d be fastest to hit the “fire photo torpedoes” button, probably because of her situation.
Deep Space Nine came closest to what I would like to have seen, an anthology series on all aspects of the Federation. Watching Kirk or Ryker or whomever chasing any woman with a brow-ridge almost every week gets old after a while...
That's the series where they fired all the writers from TNG except one.