That was “a few years ago.” Most Goodwills now are eager to get them because they’re now a money-maker due to the recent advent of the state’s recycling buyback program, at $0.20/lb. or so. However, Goodwill foundations are regional and vary according to management strategies, and it may be the one in your area isn’t interested. That’s especially true for larger TVs, because large CRTs are heavy and thus dangerous to lift—some have imposed size limits for that reason, such as 25” or 27”.
We have a pair of guys who advertise on Craigslist and will come and pick up any recyclables. I always call them now.