May have been them but could have been one of the imperial powers from just over the threshold of the age of literacy — the Elamites (who had a writing system, but it can’t be read, so far) would be a guess. The Indo-Europeans entered Europe and the Middle East (and India, for that matter) in a series of waves, which at least in part coincide with the global climate cycles.
There is an Elamite king mentioned in Genesis 14, and a mention of Elamites in Acts 2.9 (present in Jerusalem).