You might become "Windows illiterate", but Windows literacy consists largely of memorizing hundreds of hacks and workarounds specific to remediating the endemic flaws of the operating system. A Mac user would have no particular problem switching to a Linux PC. ;)
I would. I'm totally spoiled now. I've had to dip into a shell once (as aside from going to shell just to play with UNIX), but only because I wanted some esoteric power management settings.