She was on the USA TV version of "Le Femme Nikita".
Her name is Alberta Wilson.
http://us.imdb.com/name/nm0914491/
The love interest is Kim Raver.
http://us.imdb.com/name/nm0914491/
Yes... Joel Surnow and Robert Cochran wrote a great show in "La Femme Nikita." It was based on the French movie of the same title but the heroine, played by Peta Wilson was really revolted by working for the "good guys." Their morally ambiguous tactics offended her sense of justice - plus the way they blackmailed her with death to keep her in the business. It was cancelled after five seasons but still has a cult following.