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Hemp nanosheets could be better than graphene for making the ideal supercapacitor
Kurzweil Accelerating Intelligence ^ | June 16, 2015

Posted on 06/17/2015 2:21:57 AM PDT by 2ndDivisionVet

As hemp makes a comeback in the U.S. after a decades-long ban on its cultivation, scientists are reporting that fibers from the plant can pack as much energy and power as graphene, long-touted as the model material for supercapacitors, according to David Mitlin, Ph.D.

Supercapacitors are energy storage devices that have huge potential to transform the way future electronics are powered. Unlike today’s rechargeable batteries, which sip up energy over several hours, supercapacitors can charge and discharge within seconds. But they normally can’t store nearly as much energy as batteries, an important property known as energy density.

One approach researchers are taking to boost supercapacitors’ energy density is to design better electrodes. Mitlin’s team has figured out how to make them from certain hemp fibers — and they can hold as much energy as the current top contender: graphene.

“The key advantage is that our electrodes are made from biowaste using a simple process, and therefore, are much cheaper than graphene.”

His process uses hemp bast fibers. The fibers come from the inner bark of the plant and often are discarded from Canada’s fast-growing industries that use hemp for clothing, construction materials and other products. The US could soon become another supplier of bast.

His team found that if they heated the fibers for 24 hours at a little over 350 degrees Fahrenheit, and then blasted the resulting material with more intense heat, it would exfoliate into carbon nanosheets.

Mitlin’s team built their supercapacitors using the hemp-derived carbons as electrodes and an ionic liquid as the electrolyte. Fully assembled, the devices performed far better than commercial supercapacitors in both energy density and the range of temperatures over which they can work. The hemp-based devices yielded energy densities as high as 12 Watt-hours per kilogram, two to three times higher than commercial counterparts. They also operate over an impressive temperature range, from freezing to more than 200 degrees Fahrenheit.

They’re presenting their research, which a Canadian start-up company is working on scaling up, at the 248th National Meeting & Exposition of the American Chemical Society (ACS), the world’s largest scientific society.

Mitlin, who conducted the research while at the University of Alberta, received funding from Alberta Innovates Technology Futures, National Institute for Nanotechnology (Canada) and Alberta Livestock and Meat Agency.


TOPICS: Agriculture; Business/Economy; Computers/Internet; Science
KEYWORDS: batteries; electrolyte; electrolytes; energy; graphene; hemp; legalizeit; liquidelectrolyte; supercapacitors
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1 posted on 06/17/2015 2:21:57 AM PDT by 2ndDivisionVet
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To: 2ndDivisionVet

Wait ... what?


2 posted on 06/17/2015 2:46:47 AM PDT by ClearCase_guy (Claire Wolfe should check her watch. It's time.)
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To: ClearCase_guy

Don’t Bogart that nanosheet, my friend; pass it over to me.


3 posted on 06/17/2015 2:49:58 AM PDT by NonValueAdded (I love it when we're Cruz'in together)
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To: 2ndDivisionVet
His team found that if they heated the fibers for 24 hours at a little over 350 degrees Fahrenheit, and then blasted the resulting material with more intense heat, it would exfoliate into carbon nanosheets.

Supercapacitor Brownies?

4 posted on 06/17/2015 3:15:38 AM PDT by Yo-Yo (Is the /sarc tag really necessary?)
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To: 2ndDivisionVet

5 posted on 06/17/2015 3:18:01 AM PDT by Samurai_Jack (War is cruelty, there is no use trying to reform it; the crueler it is, the sooner it will be over.)
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To: 2ndDivisionVet
The hemp-based devices yielded energy densities as high as 12 Watt-hours per kilogram, two to three times higher than commercial counterparts.

Meanwhile, gasoline has an energy density of 12,200 Wh/kg.

6 posted on 06/17/2015 3:44:41 AM PDT by PapaBear3625 (You don't notice it's a police state until the police come for you.)
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To: PapaBear3625

Wikipedia lists a lead acid battery at 33-42 Wh/kg.


7 posted on 06/17/2015 4:25:54 AM PDT by KarlInOhio (The 1st amendment is the voice and the 2nd is the teeth of freedom. Obama wants to knock out both.)
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To: 2ndDivisionVet; rdb3; Calvinist_Dark_Lord; JosephW; Only1choice____Freedom; amigatec; ...

8 posted on 06/17/2015 4:27:16 AM PDT by ShadowAce (Linux -- The Ultimate Windows Service Pack)
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To: 2ndDivisionVet

So, they make graphene from hemp, and it’s more efficient than, er, graphene?


9 posted on 06/17/2015 4:33:27 AM PDT by Riflema
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To: ClearCase_guy

Think I got some hemp nano sheets from Ikea. Very nice.


10 posted on 06/17/2015 4:34:29 AM PDT by Flick Lives ("I can't believe it's not Fascism!")
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To: Riflema

This process seems to be MUCH LESS expensive than making graphene and almost as efficient in this use.


11 posted on 06/17/2015 4:37:10 AM PDT by 2ndDivisionVet (You can help: https://donate.tedcruz.org/c/FBTX0095/)
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To: PapaBear3625

I fully get your point. However, you can’t recharge gasoline. Then again, it would take more than a thousand charges for it to equal one gasoline “discharge”.


12 posted on 06/17/2015 5:03:25 AM PDT by cuban leaf (The US will not survive the obama presidency. The world may not either.)
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To: 2ndDivisionVet
Who knew it would run on doobie power?



13 posted on 06/17/2015 5:51:05 AM PDT by Buckeye McFrog
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To: 2ndDivisionVet
Well, here you go...
14 posted on 06/17/2015 5:51:47 AM PDT by Noumenon (Resistance. Restoration. Retribution.)
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To: PapaBear3625

Most people have no idea about the energy density of modern liquid fuels and how that affects their everyday lives. And what it might mean not to have any.


15 posted on 06/17/2015 5:55:54 AM PDT by Noumenon (Resistance. Restoration. Retribution.)
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To: cuban leaf
I fully get your point. However, you can’t recharge gasoline.

You can "recharge" your gas tank in a couple of minutes at a filling station, versus recharging your battery in however long it takes, from electricity that was mostly generated by fossil fuel.

16 posted on 06/17/2015 6:56:30 AM PDT by PapaBear3625 (You don't notice it's a police state until the police come for you.)
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To: PapaBear3625

I have read of graphene capacitors in the 35 Wh/Kg range. While the hemp based capacitors may be cheaper, are they 3 times cheaper?


17 posted on 06/17/2015 7:01:32 AM PDT by RightOnTheBorder
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To: PapaBear3625

I’m with you. Ever since I learned, about 25 years ago, how much energy is in a “pound of battery” vs a “pound of gasoline” I stopped being an advocate of electric power, unless the power comes from solar cells, etc.

The ONLY thing special about modern electric cars and hybrids is the ability to reclaim energy when slowing down. Period.


18 posted on 06/17/2015 7:09:13 AM PDT by cuban leaf (The US will not survive the obama presidency. The world may not either.)
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To: 2ndDivisionVet

...... but you’ll get arrested by the DEA if you try to grow any nanosheets.


19 posted on 06/17/2015 7:52:47 AM PDT by Still Thinking (Freedom is NOT a loophole!)
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To: 2ndDivisionVet; dayglored; ShadowAce

The computer clock freezes at 4:20.


20 posted on 06/17/2015 10:06:33 AM PDT by martin_fierro (< |:)~)
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