PV=nRT ?
Nope.
PV=nRT 8s the Ideal Gas Law.
It does not apply to solutions.
That is involved, but this is for two phase two component (H2O , CO2) system at two different temperatures. So it depends on the components esp water being polar.
That’s it.
PV=nRT ?
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Correct. I like [P = ρRT]. Fun with the equation of state:
So, we have the 1st law of thermodynamics,
[dQ = Cp(dT) - dP/ρ],
and, the equation of state, [P = ρRT].
Now, ρ = P/RT, substitute into 1st law of thermodynamics.
dQ = Cp(dT) - RTdP/P.
Set dQ = 0, no change in internal heat from condensation.
Now, Cp(dT) - RT(dP/P) = 0.
Or, Cp(dT/T) = R(dP/P). Integrate both sides,
Cp∫(dT/T) = R∫(dP/P). After integration,
(Cp/R) ln(T) limit: |To-θ = ln(P) limit: |Po-P(1013).
Now, ρ = P/RT, and dP/dz = -ρg (hydrostatic equation).
dP/dz = -Pg/RT, hold temperature T constant.
dP/P = -g(dz)/RT, integrate,
ln(P0/P1) = -gz/RT, exponentiate both sides,
P0 = P1•exp(-gz/RT).
Shocker! Coca cola, set out in the sun, foams in your mouth!
Does nobody work in the heat anymore?