Just that Valentine had found a doctor who agreed to prescribe Ivermectin. It appears that was AFTER he'd contracted Covid:
After Phil Valentine tested positive for COVID-19 but prior to his hospitalization, he told his listeners to consider, “If I get this COVID thing, do I have a chance of dying from it?” If so, he advised them to get vaccinated. He said he made the decision not to get vaccinated because he thought he probably wouldn’t die.
Phil Valentine also said that he was “taking vitamin D like crazy” and had found a doctor who agreed to prescribe ivermectin, a drug primarily used to treat parasites in animals.
The "also said" is apparently part of the radio conversation from the preceding paragraph.
I haven't been able to locate a story saying Valentine was taking Ivermectin preventatively.