Iron rusted so copper sheathing the iron was tried, however galvanic interaction between the metals was even worse. They then tried wooden planking between the iron and the copper. The link above is very informative.
My understanding was that 1700s sailing ships were cased in copper to prevent damage caused by the Teredo worms.
Also, British ships off the Vancouver isles had to post guards as the native Indians would swim out and pry off the copper plates to use in some of their art and rituals.
Probably the same thought when the German ME-262 first flew up to attack the B-17's.