Having Start TRek TNG rank above ALL the original series Star Treks disqualifies this list from being taken seriously. I would put the Tribble episode in the list. For Burns and Allen, I would include the Kleebob episode. For the Honeymooners, “Better Living through Television” (aka “Can it core a apple?”).
“Fall Out” from the Prisoner is “great” only in a delphic way. Most unsatisfying for most who watched the series.
Excuse me, but I think you need to take a closer look at TNG's Counselor Troi.