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No.
In all likelihood, the "black goo" was thiosulfide rubber -- the actual fuel in the solid propellant -- to which Thiokol added ammonium perchlorate as an oxidizer.
Then, they filled the rocket casings with the goo and vulcanized it in place in giant autoclaves...
The vulcanized rubber+oxidizer solid propellant looked like black, rubber shoe heel material. Thiokol engineers would demonstrate the precision of their fuel/oxidizer mix by lighting a small cube of it atop a white, glazed ceramic tile -- and showing that there was zero residue (not even discoloration) left...
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You were walking on un-vulcanized (probably raw, without oxidizer) solid rocket fuel, itself.
You have FReepMail...