Gold finger was the best, followed closely by From Russia With Love. I fell in love with Tilley and the Russian lady. Later Bond movies were a bit ridiculous. Odd Job was the best villain.
The more recent bond villains have been more realistic. In Quantum of Solace, an Al Gore clone plotted to take over Bolivia's water. In the most recent, Blofeld was installing an Internet surveillance system into nine countries. They are mostly just rich progressives working out their fantasies.