“Early Oxygen Rich Atmosphere? Origins of Sulfur in Rocks Tells Early Oxygen Story, Science Daily, April 2009. “
Uh, this dates to 2.4 billion years ago. This is after the formation of the oxygen producing organsims.
"...the redux state of the Earth's mantle has not changed in the past 3.8 Gyr." Zahnle, Schaefer, Fegley, "Earth's Earliest Atmosphere", Cold Spring Harbor Perspectives in Biology" (2010).