C:\Users\yourusername\Favorites
If you use Outlook or a local eMail client, don't forget that too!
Copy down all of the keys for your purchased software before your Toshiba dies. You'll need them for reinstalling.
I like the idea of a 32 or 63 GB SD card. Make sure to get a Class 6 or above (much faster xfer).
You can download Microsoft SyncToy here - nice free tool to sync or backup data between devices.
do most new (demo) computers not come with a disk?
(mine came loaded wuth 8.1, but no disk)