It reminded me of another of my fave all-time shows, She Spies, which had a limited run on NBC in 2000 before going to syndication. That isn't surprising since She Spies was obviously inspired by the success of the film version of Charlie's Angels, which starred Cameron Diaz, Drew Barrymore, and Lucy Liu. The director of Charlie's Angels -- which, by the way, I flipped off after ten minutes -- was directed by Joseph McGinty Nichol, bka "McG." McG is the creator and director of Chuck.
She Spies' first two seasons are as great as any show I have ever seen. While it was inspired by McG's Angels flick, it was funnier and wittier. It was more like a hybrid of the original Charlie's Angels TV show and, believe it or not, The Monkees, sharing that classic comedy's penchant for "breaking the fourth wall" (IOW, the actors break character to address the viewer).
Unfortunately, the lighthearted action in She Spies ended in the third season, and the producers tried to make it more like Mission Impossible meets Baywatch. Ugh. I saw the third season's premiere and never watched it again. Apparently, I wasn't alone, as it was the final season.