"Appropriate physical action of the brain evokes awareness" -- Roger Penrose
He says that some (but not all) of the inquiry into consciousness is beyond science
"My own position is that the questions of the mind, though they lie uncomfortably with present-day scientific understanding, should not be regarded as being forever outside the realm of science." --Roger Penrose
Penrose believes it is beyond our current understanding of science. Few materialists would disagree with that. Penrose does not believe that it will always be so.
No doubt there is much overlapping between the term materialism and physicalism - which no doubt leads to their being interchanged in common usage. But like the previous discussion on observer, the words have a technical meaning, and you made the distinction in what you said:
Penrose believes it is beyond our current understanding of science. Few materialists would disagree with that. Penrose does not believe that it will always be so.