It's as hard to explain to them as the precession of the Earth's spin, and changes in orbital progress around the Sun. There's a lot on Earth, like Global Warming and Cooling, with which we simply have nothing to do.
Depends on what kind of pollution you're talking about. Sulfur dioxide and ash, yes; carbon dioxide, no. SO2 emissions from volcanoes are on par with human emissions (primarily from coal burning) -- obviously they put out a lot of ash -- but they aren't a significant source of CO2.