My sister-in-law shops a lot at Goodwill and I can truthfully say, although they are used, she gets some pretty nice clothes there and wears them well. Just saw her in a leather jacket (I assumed it was real leather) which she said cost her $12.00 (not bad).
She did say that some Goodwill stores have better clothes than others and stated, “It costs more to go first class” but what she buys looks pretty good on her.