DUDE! They are NOT interchangeable!
Precisely Laz. The 5.56 has a longer leade. The leade is the part of the barrel immediately in front of the chamber where the bullet travels before engaging the rifling.
Bad things can happen if you try to fire 5.56 through a .223 barrel.
The type of barrel you have should be roll stamped on the barrel.
Fire .223 through a 5.56 barrel all you want.