There were some 2 seat versions built mainly to make it easier to train new pilots.
Originally the A-10s(CIA) and SR 71s(Air Force) were single seaters
You are correct about the CIA 'A'rchangel being single-seat but the only built versions were the '12' versions; A-12, YF-12A and then the M-21 (launch platform for D-21 drone). The YF-12A was the USAF designation for the Interceptor version of this airframe and identifiable by the nose lacking the smooth chines of the other models to accommodate the Hughes AN/ASG-18 fire-control radar. However the 3 YF-12As were all two-seaters, pilot & radar operator. Two of the YF-12As were lost but the remaining one is at Wright-Patterson USAF Museum in Dayton, OH.
The 9 surviving A-12s are on display at the following locations;
A-12 60-6924 at the Air Force Flight Test Center Museum Annex, Blackbird Airpark, at Plant 42, Palmdale, California.
A-12 60-6925 at the Intrepid Sea-Air-Space Museum, parked on the deck of the aircraft carrier USS Intrepid, New York City.
A-12 60-6927 the two-seat trainer at the California Science Center in Los Angeles, California.
A-12 60-6930 at the U.S. Space and Rocket Center, Huntsville, Alabama.
A-12 60-6931 at the CIA Headquarters, Langley, Virginia.
A-12 60-6933 at the San Diego Air & Space Museum, Balboa Park, San Diego, California.
A-12 60-6937 at the Southern Museum of Flight, Birmingham, Alabama.
A-12 60-6938 at the Battleship Memorial Park (USS Alabama), Mobile, Alabama.
M-21 60-6940 at the Museum of Flight, Seattle, Washington.
It was the A-12 that came first.
71s were always two seater. Recon officer behind the pilot. For the trainers, they raised the rear cockpit to give it a forward view.